Synthesis and characterization of naphthalocyanines and phthalocyanines of use in sensitizer studies

James R. Sounik; Lee A. Schechtman; Boris D. Rihter; William E. Ford; Michael A. J. Rodgers; Malcolm E. Kenney

doi:10.1117/12.17668

1 July 1990 Synthesis and characterization of naphthalocyanines and phthalocyanines of use in sensitizer studies

James R. Sounik, Lee A. Schechtman, Boris D. Rihter, William E. Ford, Michael A. J. Rodgers, Malcolm E. Kenney

Proceedings Volume 1203, Photodynamic Therapy: Mechanisms II; (1990) https://doi.org/10.1117/12.17668
Event: OE/LASE '90, 1990, Los Angeles, CA, United States

Abstract

Methods for the preparation of the naphthalocyanines SiNc(OSi(n-C6H13)3)2, SiNc(OSi(i-C4H9)2n-C18H37)2, GeNc(OSi(n-C6H13)3)2, SnNc(OSi(n-C6H13)3)2, AlNcOSi(n-C6H13)3 ' and GaNcOSi(n-C6H13)3 the halonaphthalocyanine isomer mixtures SiMc(Cl)4(OSi(n-C6H13)3)2 and SiNc(Br)4(OSi(n-C6H13)3)2; and the butoxyphthalocyanines GePc(0-n-C4H9)g(OSi(C2H5)3)2 , SnPc(O-n-C4H9)8(OSi(C2H5)3)2, Al(O-n- C4H9)8OSi(C2H5)3 , Ga(O-n-C4H9)8OSi(C2H5)3 , PdPc(O-n-C4H9)8, and Ru(O-n- C4H9)8(C6H5N)2 are outlined. Ultraviolet-visible spectra and other properties of these compounds are described, and their potential as sensitizers is touched upon.

Citation Download Citation

James R. Sounik, Lee A. Schechtman, Boris D. Rihter, William E. Ford, Michael A. J. Rodgers, and Malcolm E. Kenney "Synthesis and characterization of naphthalocyanines and phthalocyanines of use in sensitizer studies", Proc. SPIE 1203, Photodynamic Therapy: Mechanisms II, (1 July 1990); https://doi.org/10.1117/12.17668

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