This work is devoted to investigation of the spectral and luminescent properties of lithium-germanate, lithium-sodium germanate and lithium-zinc-germanate glass ceramics obtained by high-temperature heat treatment of the initial glass doped with manganese and chromium ions. It is shown that when sodium is added to Mn-doped lithium germanate glass-ceramics, the luminescence intensity of Mn4+ ions increases from 5 to 37% of the quantum yield. In lithium-zinc-germanate glass-ceramics, the simultaneous presence of Mn4+ ions in an octahedral environment with red luminescence near 670 nm and Mn2+ ions in a tetragonal environment with long persistent green luminescence at 540 nm is found. The maximum quantum yield for red luminescence was 47%, for green luminescence – 23%. The intensity ratio of different luminescence bands depends on the ratio of lithium / zinc ions in the glass composition. In all studied glass-ceramics, Cr3+ ions demonstrate weak luminescence with a maximum in the region of 690–698 nm. The possibility of using the materials under study as a luminescent red radiation source material is considered.
This work is devoted to the study of phase transitions in CsPbBr3 perovskite nanocrystals nucleated in borogermanate glass. Perovskite nanocrystals are obtained by bulk crystallization in a glass matrix. A series of glass samples with nanocrystals of different sizes is investigated. Upon heating, the temperature dependence of the 1S exciton intensity for the entire series of samples shows the presence of three phase transitions: in the range 130-150, 440-450, and 510-515°C. The first phase transition refers to the transition from a tetragonal to a cubic structure. The last phase transition is associated with the melting of the crystalline phase. The phase transition at 440°С is declared for the first time. Upon cooling, the temperature curve shows the presence of only one phase transition in the region of 330°C, which is associated with the crystallization onset of CsPbBr3 perovskite nanocrystals in glass matrix.
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