Quartz-enhanced photoacoustic spectroscopy (QEPAS) is a highly sensitive optical technique, suitable for real-time and in situ trace gas detection. In QEPAS, Quartz tuning forks (QTF) are employed as piezoelectric transducers of sound waves, induced by gas non-radiative energy relaxation following an infrared modulated light absorption. The generated electric signal depends on the gas concentration. An accurate and reliable QEPAS measurement requires: i) the QTF characterization, in terms of resonance frequency and quality factor and ii) the tuning range scan of the laser employed to detect the selected gas. These two operations could take several minutes. Beat frequency QEPAS (BF-QEPAS) is an alternative approach to standard QEPAS. In BF-QEPAS, a fast scan of the laser tuning range is employed to generate an acoustic pulse. Gas concentration, QTF resonance frequency, and quality factor can be measured acquiring and analyzing the transient response of the QTF to the acoustic pulse. In this work, a custom T-shaped QTF was employed to detect nitrogen monoxide (NO), targeting its absorption feature at 1900.07 cm-1 with an interband cascade laser. A minimum detection limit as low as 180 ppb of NO at an integration time of 5 ms was achieved, and a highly accurate measurement of the QTF resonance frequency and quality factor were demonstrated using BF-QEPAS. Finally, the possibility to fully scan the laser tuning range in less than 15 s was proved.
Simultaneous detection of different gas species represents an indispensable asset for several applications, such as instantaneous quantification of isotope concentration ratios, self-calibrating sensors, and monitoring of the temporal evolution of a chemical reaction. In this research work, a dual-gas quartz-enhanced photoacoustic spectroscopy (QEPAS) sensor for a real-time analysis and in a continuous flow monitoring of one reactant and one product of a gas-phase chemical reaction involving nitrogen dioxide (NO2) and water vapor (i.e., H2O) – as reaction reactants – and nitrogen monoxide (NO) – as one of the reaction products – was realized. The QEPAS sensor implemented a spectrophone composed of a pair of metallic acoustic resonator tubes applied at both antinode points of a custom quartz tuning fork (QTF). In this configuration, two different quantum cascade lasers (QCLs) were used, having an emission wavelength centered at 5.26 μm – resonant with a nitrogen monoxide absorption feature located at 1,900.075 cm-1 – and at 6.25 μm – resonant with a nitrogen dioxide absorption feature located at 1,601.77 cm-1 –, respectively. The chemical reaction was studied by injecting in the gas line a certified concentration of 5,000 parts-per-million (ppm) of NO2:N2 and monitoring the QEPAS signals at four different total gas flow values, i.e., 10, 20, 30 and 50 standard cubic centimeters per minute (SCCM), respectively.
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