Chalcogenides are a material platform for infrared nonlinear optics with high transmission and nonlinearity, but are susceptible to changes in bond structure during fabrication. These changes affect both the linear and nonlinear optical properties of the chalcogenide. We analyze the structure and optical properties of thermally evaporated and annealed Ge28Sb12Se60 to determine why these changes occur and how they can be rectified. We observe that thermally evaporated Ge28Sb12Se60 has an increased selenium content, increased bandgap, increased concentration of heteropolar bonds, and lower third order nonlinearity. We further observe that annealing above the glass transition temperature reduced the concentration of heteropolar bonds and increased the third order nonlinearity by a factor of four.
Access to the requested content is limited to institutions that have purchased or subscribe to SPIE eBooks.
You are receiving this notice because your organization may not have SPIE eBooks access.*
*Shibboleth/Open Athens users─please
sign in
to access your institution's subscriptions.
To obtain this item, you may purchase the complete book in print or electronic format on
SPIE.org.
INSTITUTIONAL Select your institution to access the SPIE Digital Library.
PERSONAL Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.