Dr. Mikhail V. Lebedev Profile

Dr. Mikhail V. Lebedev

at Ioffe Institute

SPIE Involvement:

Author

Publications (1)

This will count as one of your downloads.

You will have access to both the presentation and article (if available).

DOWNLOAD NOW

This content is available for download via your institution's subscription. To access this item, please sign in to your personal account.

Email or Username Forgot your username?

Password Forgot your password?

Show

Keep me signed in

No SPIE account? Create an account

Proceedings Article | 25 January 2007 Paper

Chemical control over surface atomic structure and electronic properties of III-V semiconductors

Mikhail Lebedev

Proceedings Volume 6596, 65960Z (2007) https://doi.org/10.1117/12.726476

KEYWORDS: Annealing, Ionization, Gallium, Molecules, Sulfur, Semiconductors, Adsorption, Chemical species, Arsenic, Ions

Read Abstract +

A new approach to control chemically the atomic structure and electronic properties of III-V compound semiconductors is developed. This approach is based on the modification of chemical properties of anionic adsorbates (such as HS^- ions) prior to their adsorption on the surface. This is achieved through the solvation of the ions with different amphiprotic solvents (water, alcohols). Ab initio quantum-chemical calculations show that the reactivity of solvated HS^- ions depends essentially on composition of the solvation shell: hydrated ions are slightly electrophilic, whereas ions solvated by alcohols are nucleophilic. Mechanism of interaction of such solvated ions with the semiconductor surface depends on the solvent solvating the ion. Experimentally it is found that on adsorption of HS^- ions from different solvents the As-S bonds with solvent-dependent ionicity are formed on the surface. These surfaces possess different ionization energy and electronic properties though now traces of solvent molecules are found in XPS spectra.

My Library

You currently do not have any folders to save your paper to! Create a new folder below.

Folder Name

Folder Description

View contact details

UPDATE YOUR PROFILE

Is this your profile? Update it now.

Sign into your SPIE.org account

Don’t have a profile and want one?

Create an account on SPIE.org

Access to the requested content is limited to institutions that have purchased or subscribe to SPIE eBooks. You are receiving this notice because your organization may not have SPIE eBooks access.*

*Shibboleth/Open Athens users─please sign in to access your institution's subscriptions.

To obtain this item, you may purchase the complete book in print or electronic format on SPIE.org.

ORGANIZATIONAL
Sign in with credentials provided by your organization.

Organizational Username

Organizational Password

Show/Hide Password

INSTITUTIONAL
Select your institution to access the SPIE Digital Library.

SELECT YOUR INSTITUTION

PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.

PERSONAL SIGN IN

No SPIE Account? Create one

PURCHASE THIS CONTENT

SUBSCRIBE TO DIGITAL LIBRARY

50 downloads per 1-year subscription

Members: $195

Non-members: $335 ADD TO CART

25 downloads per 1 - year subscription

Members: $145

Non-members: $250 ADD TO CART

PURCHASE SINGLE ARTICLE

Includes PDF, HTML & Video, when available

Members:

Non-members: ADD TO CART

Keywords/Phrases

Search In:

Publication Years