TeO2 based glasses with the molar composition (70-x-y)TeO2-20WO3-10Y2O3-xEr2O3-yYb2O3, where x = 0 and 0.5 mol% and y = 0, 0.5, 1, 2 and 4 mol%, were prepared by the melt quenching technique. The Raman spectra of the vitreous samples, using laser excitation line of 532 nm showed a band distribution related with Te-O and W-O bond vibrations. The introduction of WO3 results in a higher bandwidth relatively to SiO2 based glasses and even other TeO2 based glasses, making this vitreous system promising for Raman optical amplification. The use of UV laser excitation line of 325 nm induced surface modifications on the samples.
Wide band gap oxide media including 4fn or 3dn ions attracts a considerable attention in the context of photonics and bio-photonics applications due to the electromagnetic widespread spectral range covered by the intraionic radiative relaxation of the charged lanthanide and transition metal ions. Converting ultraviolet commercial light into visible luminescence continues to raise interest for the solid state light market, justifying the demand for new and efficient phosphors with wide spectrum coverage and improved thermal quenching behavior. New materials and methods have been thoroughly investigated for the desired purposes. In this work, we report on laser processing for the growth of oxides media such as ZrO2, ZnO among other oxide hosts. The transparent crystalline materials in-situ doped with different amounts of lanthanide or transition metal ions are explored in order to enhance the room temperature ions luminescence by pumping the samples with ultraviolet photons. Spectroscopic studies of the undoped and doped oxide hosts were performed using Raman spectroscopy, photoluminescence (PL) and photoluminescence excitation (PLE).
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