Tip-enhanced Raman spectroscopy and microscopy are performed on a single nitrogen atom, carbon monoxide, pyridine, and benzene adsorbed on the Cu(100) surface. As the complexity of system ranging from an atomic vibrator to polyatomic molecules increases, the collective information gained from individual experiments elucidates the governing mechanism of Raman scattering in the atomistic near-field from different angles. Rich physics observed from above-mentioned systems such as dielectric screening, concomitant electromagnetic and chemical enhancement, Stark shift, dehydrogenation, and distortion and recovery of vibrational information will be discussed.
Access to the requested content is limited to institutions that have purchased or subscribe to SPIE eBooks.
You are receiving this notice because your organization may not have SPIE eBooks access.*
*Shibboleth/Open Athens users─please
sign in
to access your institution's subscriptions.
To obtain this item, you may purchase the complete book in print or electronic format on
SPIE.org.
INSTITUTIONAL Select your institution to access the SPIE Digital Library.
PERSONAL Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.