We investigate the degradation of high-periodicity GaN-based InGaN-GaN multiple quantum wells (MQWs) solar cells submitted to stress under high excitation intensity and high temperature; stress conditions are chosen to investigate cell behavior in a harsh scenario, such as wireless power transfer systems, space applications and concentrator harvesting systems. By examining the decrease in the short-circuit current and electroluminescence of these devices and the increase in the forward current at low bias, we suggest the presence of a thermally-activated diffusion process of impurities from the p-side of the device toward the active region. This process favors the increase in the Shockley-Read- Hall (SRH) recombination rate. By employing the van Opdorp and t’Hooft model, we analyzed the time-variation of non-radiative Shockley-Read-Hall lifetime during aging, extracting the diffusion coefficient of the defect involved in the degradation; we also extracted the related activation energy by an appropriate fitting of the degradation kinetics according to Fick’s second law of diffusion. The obtained values suggest that degradation originates from the diffusion of hydrogen, whose severity depends also on the thickness of the p-GaN layer of these devices. The proposed analysis methods and the obtained results are useful for understanding the physics of multiple quantum wells (MQWs) solar cells during degradation. The results can be used to increase the performance and reliability in novel applications where these devices are proposed, such us additional layer in multi-junction (MJ) solar cells, and the application in harsh environments.
GaN-based multi-quantum wells solar cells could be breakthrough devices for extreme applications like space environment and harsh photovoltaics. We performed a forward-bias stress on samples with 30 quantum wells with 15% indium content to better understand degradation mechanisms. DUTs were characterized by means of dark and illuminated IV, CV and Steady-State Photocapacitance measurements. First, we performed a step-stress experiment, by increasing current in 30 minutes steps up to 500 mA, when the device failed. We observed a variation in series resistance, a decrease in shunt resistance and a strong decrease in EQE, conversion efficiency and open-circuit voltage, especially at low excitation intensities. CV measurements showed an increase and then a decrease in free charge density in the device, that was correlated to the variation in trap-states density evaluated by SSPC. Based on the results of this step-stress experiment, we carried out a 100 hours constant-current stress at 40 mA. This stress showed a moderate decrease in series resistance and a decrease in EQE and conversion efficiency. An increase in charge density was observed and correlated with the decrease in conversion efficiency. The degradation of the device was related to the generation of defects, that may create a nearmidgap states, detected by SSPC measurement, and a shallow donor state that generates a change in free carrier density. These defects possibly migrate through the devices, as they are detected at different times by SSPC and CV measurements.
GaN-based solar cells are promising devices for application in space environment, concentrator solar systems and wireless power transmission. Thus, it is essential to understand their degradation kinetics when submitted to high-temperature, high-intensity stress. We submitted GaN-based multiple-quantum-well solar cells with AlGaN electron-blocking-layer to two step-stress experiments at 35 °C and 175 °C in short-circuit condition under 405 nm monochromatic excitation by increasing optical power from 47 W/cm2 to 375 W/cm2. We found almost no degradation in the dark-IV, light-IV, electroluminescence and photocurrent characteristics after low-temperature stress, whereas the degradation after hightemperature stress was significant: we observed a lowering in power-conversion efficiency, a decrease in open-circuit voltage and an increase in low forward bias current. We then submitted the device to several constant power stress at 180 W/cm2 for 100 hours at 95 °C, 135 °C and 175 °C. We found that, by increasing the temperature, the short-circuit current during the stress decreased of 7%, 9% and 12.5% respectively. Dark IV characteristics showed an increase in low-forward bias current stronger at 175 °C. We also found a higher decrease in open-circuit voltage, external quantum efficiency, power conversion efficiency and electroluminescence with higher stress temperature. The causes of degradation are possibly diffusion mechanisms, which increase defect density in the p-GaN bulk region and/or in the GaN barrier region, promoting trap-assisted tunneling mechanisms, leading to the decrease in open-circuit voltage, and non-radiative recombination mechanisms, that cause the drop in quantum efficiency.
We present an investigation on the stability of high periodicity (30 pairs) multiple quantum well InGaN-GaN devices for photodetection and light harvesting in the UV and visible spectral range. The devices under test were characterized during optical stress by I-V measurements in dark condition and illuminated with a monochromatic LD emitting at 405 nm with intensities ranging from 1 mW/cm2 to 50 W/cm2. We submitted the devices to several step-stress experiments: a first one in short-circuit condition at 100 °C baseplate temperature with monochromatic excitation from 361 W/cm2 to 1164 W/cm2; a second one at fixed optical power of 589 W/cm2 and baseplate temperature increasing from 35°C to 175 °C. We also evaluated the carrier flow induced degradation by means of a current stress, ranging from 1 A/cm2 to 14 A/cm2 , without optical excitation. We then performed a 50 hours stress at 175 °C baseplate temperature and 589.3 W/cm2 excitation. During this stress the open-circuit voltage and the optical-to-electrical conversion efficiency significantly decreased, especially at low characterization intensities, whereas short-circuit current and external quantum efficiency showed almost no variation.
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