Paper
5 September 2014 Optical characterization of ferroelectric PZT thin films by variable angle spectroscopic ellipsometry
Md. Shafiqur Rahman, Carlos D. Garcia, Amar Bhalla, Ruyan Guo
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Abstract
Ferroelectric thin films are used as high dielectric constant capacitors, infrared detectors, piezoelectric transducers, optical modulators, optical waveguides, and nonvolatile memory chips for dynamic random access memory (DRAM) etc. While ferroelectric and dielectric properties of these films have been extensively investigated, their optical properties have been comparatively less studied and of limited use in quantitative evaluation of multilayer thin films. In this work we explored the variable angle spectroscopic ellipsometry (VASE) technique for its effectiveness in physical property characterization. The VASE combined with its computer modeling tool enables nondestructive, nonintrusive, and contactless optical means for optical characterization. Crystalline Lead Zirconium Titanate PbZr0.52Ti0.48O3 (PZT) thin films, fabricated on SrTiO3 layer atop of Si substrates, were characterized using VASE (J.A. Woollam; Lincoln, NE, USA) by determining the ellipsometric parameters Ψ and Δ as a function of wavelengths (200-1000 nm) and incident angles (65°, 70°,75°) at room temperature. A physical representation of the multilayer system was constructed by a six layer model (analysis software WVASE32, J.A. Woollam) through a step-by-step method. Other physical properties characterized by several well-known techniques on structure, morphology and topographical features correspond well with the models developed using VASE alone. The technique and the methodology developed have shown promises in identifying the respective thickness and optical properties of multilayer thin film system, with limited input of processing or composition information.
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Md. Shafiqur Rahman, Carlos D. Garcia, Amar Bhalla, and Ruyan Guo "Optical characterization of ferroelectric PZT thin films by variable angle spectroscopic ellipsometry", Proc. SPIE 9200, Photonic Fiber and Crystal Devices: Advances in Materials and Innovations in Device Applications VIII, 92000A (5 September 2014); https://doi.org/10.1117/12.2064658
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KEYWORDS
Ferroelectric materials

Thin films

Refractive index

Crystals

Dielectrics

Silicon

Spectroscopic ellipsometry

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