Hydrogen energy is widely used as one of the cleanest energy sources. However, due to its explosive nature, monitoring the early stages of hydrogen leakage has become a current research focus. This study presents a novel hydrogen sensor suitable for low concentration hydrogen sensing, which combines a planar polymer Bragg grating (PPBG) with a porous Pt/WO3 hydrogen sensitive material modified by MIL-100 (Fe) as a template. PPBG are based on planar cyclo-olefin copolymer substrates with integrated waveguides and Bragg gratings. Due to the polymer's inherently increased coefficient of thermal expansion, the concept provides superior thermal sensitivity. Porous Pt/WO3 has a larger specific surface area and better response characteristics than the original Pt/WO3. By utilizing the thermal effect of the reaction between tungsten trioxide and hydrogen gas, the wavelength shift of PPBG is caused by temperature transformation. A series of experimental results tested at different hydrogen concentrations indicates the sensitivity of the sensor is 575 pm/%. The combination of materials and devices with superior performance enhances the sensitivity of the sensor to hydrogen at low concentrations compared with fiber Bragg grating (FBG) hydrogen sensors. The hydrogen sensor has the advantages of high sensitivity at low concentrations and compact structure, which will have great potential in industrial applications.
While sapphire is one of the most durable materials, its properties entail that high-precision machining, especially in the sub-millimeter regime, is still challenging. This contribution demonstrates and discusses novel femtosecond laser-based micromachining approaches for the fabrication of rotational-symmetric sapphire workpieces, specifically the generation of optical fibers by means of laser lathe of sapphire rod and the practical realization of windmill fibers. In addition, refractive index modification in planar sapphire substrates is presented to induce photonic crystal waveguides. The micromachined structures are comprehensively examined with respect to geometric fidelity, surface roughness, refractive index modification, and potential optical waveguiding properties. All micromachining approaches are done by means of frequency-doubled or frequency-tripled femtosecond laser radiation. Different laser optical setups including laser scanning head, spatial beam profilers including a spatial light modulator and axial rotatory movement of the specimen are employed for micro structuring and in-depth refractive index modifications. In particular for laser lathe, a sophisticated scanning pattern in combination with an incremental axial rotatory movement of the specimen allows for the precise diameter reduction of sapphire rods with 250 μm diameter to fibers with outer diameters of 25 μm. By supporting the workpiece with a V-groove fixture, multi-mode fibers with lengths up to 20 cm can be processed with an average surface roughness of 250 nm. Additionally, an adapted ablation scanning sequence enables the first practical demonstration of sapphire windmill fibers. Furthermore, using a spatial light modulator allows for the adaption of the laser propagation properties as to enable volume refractive index modifications with free-form arrangement. Hexagonal patterns of refractive index modifications surrounding a pristine waveguide core are fabricated and single-mode waveguiding at 1550 nm is verified. Finally, the possibility of integrating Bragg gratings into this photonic waveguide type is demonstrated.
While Bragg grating-based optical devices have shown promising performances for pressure sensing applications, their sensitivity, especially in the low-pressure regime, is unsatisfying and needs to be optimized by elaborate designs, such as cantilevers or other extrinsic mechanical transducers. This contribution demonstrates and discusses a novel concept for optical pressure sensors based on polymer planar Bragg gratings. Waveguide and Bragg grating are fabricated underneath the surface of a temperature-stable and humidity-insensitive cyclic olefin copolymer substrate by means of a femtosecond laser. Based on the employed direct-writing procedure, in combination with adaptive, in-situ beam shaping with a spatial light modulator, writing depth, i.e., location of the photonic structures within the substrate, as well as Bragg grating periodicity and positioning can be deliberately chosen. Afterwards, the polymer substrate is post-processed with a highprecision micro mill, so a diaphragm comprising the integrated photonic structures is generated. The resulting diaphragm exhibits a thickness of 300 μm and a diameter of 10 mm. Finally, the optical sensor is packaged and sealed to form an airfilled gas pocket underneath the diaphragm. Deformations of the diaphragm by external pressure changes translate to strain variations along the waveguide axis and thus perturb the Bragg grating period. This leads to changes in the grating’s wavelength of main reflection, which can be evaluated in order to quantify the relative external pressure. With this straightforward optical sensor concept, pressure sensitivities up to 39 pm kPa-1, within relative pressures ranges from -78 kPa to 372 kPa, are achieved.
As one of the cleanest energy sources in the 21st century, the development of hydrogen energy has attracted the attention of all countries in the world, so the monitoring of hydrogen leakage has become a current research focus. This study demonstrates a novel hydrogen sensor that combines a planar polymer grating with a Pd/Ni hydrogen-sensitive material that takes advantage of the hydrogen-absorbing expansion properties of Pd to cause the central wavelength drift of Planar Polymer Bragg Grating (PPBG) by strain transformation. The experimental results show when the hydrogen concentration is 0.3%, 0.6% and 1%, the wavelength shift of the sensor is 50 pm, 85 pm and 110 pm respectively, and the response time is approximately 30 seconds. This hydrogen sensor has the advantages of high sensitivity, low cost and compact structure, leading to great potential in industrial applications.
We report on the fabrication process and the application potential of epoxy-based waveguide Bragg grating sensors on low-modulus polymer substrates for low-cost environmental seismic sensing purposes. EpoCore photoresist channel waveguides are fabricated on a highly flexible TPX polymethylpentene polyolefin substrate by means of standard i-line photolithography. Bragg gratings are permanently inscribed into the strip waveguides by KrF excimer laser irradiation using commercially available phase masks. From these raw sensor chips, a linear accelerometer sensitivity of 107 pm/g in a broadband detection range of at least 0.025 – 15 g could be observed. The enhanced seismic sensing capabilities of the Bragg grating sensor scheme are demonstrated by the use of a simple spring mass system.
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