Laser Powder Beam Fusion (LPBF)processes use laser beams to selectively melt powder layers and build three dimensional parts layer by layer. Usually, the beam has a Gaussian profile and the melt temperature peaks near the beam center. For typical conditions this temperature is well over the boiling point and drives intensive evaporation. Evaporation-driven recoil momentum can produce detrimental material spattering and keyhole porosity. Evaporation itself consumes a significant amount of energy thus degrading the process efficiency. It can therefore be beneficial to alter the beam shape so as to have the temperature distribution in the melt pool close to that of a flat top. We determined with a simple thermal model the beam shape providing a relatively flat temperature distribution . The optimal is found to be doughnut mode-like, skewed in the scan direction.
We did high fidelity simulations of the melt pool produced by the optimized beam and evaluated the possible benefits, including the efficiency increase.
We started the experiments with doughnut shape beam far from the optimal but also far from the Gaussian one. The experimental data will be compared with simulation results.
This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.
A ground-based laser system for space debris cleaning requires pulse power well above the critical power for self-focusing in the atmosphere. Self-focusing results in beam quality degradation and is detrimental for the system operation. We demonstrate that, for the relevant laser parameters, when the thickness of the atmosphere is much less than the focusing length (that is, of the orbit scale), the beam transit through the atmosphere produces the phase distortion only. The model thus developed is in very good agreement with numerical modeling. This implies that, by using phase mask or adaptive optics, it may be possible to eliminate almost completely the impact of self-focusing effects in the atmosphere on the laser beam propagation.
Localized heating of roughened steel surfaces using highly divergent laser light emitted from high-power laser diode arrays was experimentally demonstrated and compared with theoretical predictions. Polarization dependence was analyzed using Fresnel coefficients to understand the laser-induced temperature rise of HY-80 steel plates under 383- to 612-W laser irradiation. Laser-induced, transient temperature distributions were directly measured using bulk thermocouple probes and thermal imaging. Finite-element analysis yielded quantitative assessment of energy deposition and heat transport in HY-80 steel using absorptivity as a tuning parameter. The extracted absorptivity values ranged from 0.62 to 0.75 for S-polarized and 0.63 to 0.85 for P-polarized light, in agreement with partially oxidized iron surfaces. Microstructural analysis using electron backscatter diffraction revealed a heat affected zone for the highest temperature conditions (612 W, P-polarized) as evidence of rapid quenching and an austenite to martensite transformation. The efficient use of diode arrays for laser-assisted advanced manufacturing technologies, such as hybrid friction stir welding, is discussed.
Interaction of femtosecond laser pulses with a bulk glass (fused silica as an example) has been studied numerically based on non-linear Maxwell’s equations supplemented by the hydrodynamics-type equations for free electron plasma for the cases of Gaussian linearly-polarized and doughnut-shaped radially-polarized laser beams. For Gaussian pulses focused inside glass (800 nm wavelength, 45 fs duration, numerical aperture of 0.25), the free electron density in the laser-excited region remains subcritical while the locally absorbed energy density does not exceed ~2000 J/cm3 in the range of pulse energies of 200 nJ – 2 μJ. For doughnut-shaped pulses, the initial high-intensity ring of light is shrinking upon focusing. Upon reaching a certain ionization level on its way, the light ring splits into two branches, one of which shrinks swiftly toward the beam axis well before the geometrical focus, leading to generation of supercritical free electron density. The second branch represents the laser light scattered by the electron plasma away from the beam axis. The final laserexcited volume represents a tube of 0.5–1 μm in radius and 10-15 μm long. The local maximum of absorbed energy can be more than 10 times higher compared to the case of Gaussian beams of the same energy. The corresponding pressure levels have been evaluated. It is anticipated that, in the case of doughnut-shaped pulses, the tube-like shape of the deposited energy should lead to implosion of material that can be used for improving the direct writing of high-refractive index optical structures inside glass or for achieving extreme thermodynamic states of matter.
A comprehensive study of laser-induced damage associated with particulate damage on optical surfaces is presented. Contaminant-driven damage on silica windows and multilayer dielectrics is observed to range from shallow pitting to more classical fracture-type damage, depending on particle-substrate material combination, as well as laser pulse characteristics. Ejection dynamics is studied in terms of plasma emission spectroscopy and pump-probe shadowgraphy. Our data is used to assess the momentum coupling between incident energy and the ejected plasma, which dominates the laser-particle-substrate interaction. Beam propagation analysis is also presented to characterize the impact of contaminant-driven surface pitting on optical performance.
The ablation of magnetron sputtered metal films on fused silica substrates by a 1053 nm, picosecond class laser was studied as part of a demonstration of its use for in-situ characterization of the laser spot under conditions commonly used at the sample plane for laser machining and damage studies. Film thicknesses were 60 and 120 nm. Depth profiles and SEM images of the ablation sites revealed several striking and unexpected features distinct from those typically observed for ablation of bulk metals. Very sharp thresholds were observed for both partial and complete ablation of the films. Partial film ablation was largely independent of laser fluence with a surface smoothness comparable to that of the unablated surface. Clear evidence of material displacement was seen at the boundary for complete film ablation. These features were common to a number of different metal films including Inconel on commercial neutral density filters, stainless steel, and aluminum. We will present data showing the morphology of the ablation sites on these films as well as a model of the possible physical mechanisms producing the unique features observed.
Interaction of ultrashort laser pulses with transparent materials is a powerful technique of modification of material properties for various technological applications. The physics behind laser-induced modification phenomenon is rich and still far from complete understanding. We present an overview of our models developed to describe processes induced by ultrashort laser pulses inside and on the surface of bulk glass. The most sophisticated model consists of two parts. The first part solves Maxwell’s equations supplemented by the rate and hydrodynamics equations for free electrons. The model resolves spatiotemporal dynamics of free-electron population and yields the absorbed energy map. The latter serves as an initial condition for thermoelastoplastic simulations of material redistribution. The simulations performed for a wide range of irradiation conditions have allowed to clarify timescales at which modification occurs after single laser pulses. Simulations of spectrum of laser light scattered by laser-generated plasma revealed considerable blueshifting which increases with pulse energy. To gain insight into temperature evolution of a glass material under the surface irradiation conditions, we employ a model based on the rate equation describing free electron generation coupled with the energy equations for electrons and lattice. Swift heating of electron and lattice subsystems to extremely high temperatures at fs timescale has been found at laser fluences exceeding the threshold fluence by 2-3 times that can result in efficient bremsstrahlung emission from the irradiation spot. The mechanisms of glass ablation with ultrashort laser pulses are discussed by comparing with the experimental data. Finally, a model is outlined, developed for multi-pulse irradiation regimes, which enables gaining insight into the roles of defects and heat accumulation.
We report an investigation on the response to laser exposure of a protective capping layer of 1ω (1053 nm) high-reflector
mirror coatings, in the presence of differently shaped Ti particles. We consider two candidate capping layer materials,
namely SiO2 and Al2O3. They are coated over multiple silica-hafnia multilayer coatings. Each sample is exposed to a
single oblique (45°) shot of a 1053 nm laser beam (p polarization, fluence ~ 10 J/cm2, pulse length 14 ns), in the
presence of spherically or irregularly shaped Ti particles on the surface. We observe that the two capping layers show
markedly different responses. For spherically shaped particles, the Al2O3 cap layer exhibits severe damage, with the
capping layer becoming completely delaminated at the particle locations. In contrast, the SiO2 capping layer is only
mildly modified by a shallow depression, likely due to plasma erosion. For irregularly shaped Ti filings, the Al2O3
capping layer displays minimal to no damage while the SiO2 capping layer is significantly damaged. In the case of the
spherical particles, we attribute the different response of the capping layer to the large difference in thermal expansion
coefficient of the materials, with that of the Al2O3 about 15 times greater than that of the SiO2 layer. For the irregularly
shaped filings, we attribute the difference in damage response to the large difference in mechanical toughness between
the two materials, with that of the Al2O3 being about 10 times stronger than that of the SiO2.
Laser induced damage (breakdown) initiated on the exit surface of transparent dielectric materials using nanosecond pulses creates a volume of superheated material reaching localized temperatures on the order of 1 eV and pressures on the order of 10 GPa or larger. This leads to material ejection and the formation of a crater. The volume of this superheated material depends largely on the laser parameters such as fluence and pulse duration. To elucidate the material behaviors involved, we examined the morphologies of the ejected superheated material particles and found distinctive morphologies. We hypothesize that these morphologies arise from the difference in the structure and physical properties (such as the dynamic viscosity and presence of instabilities) of the superheated material at the time of ejection of each individual particle. Some of the ejected particles are on the order of 1 µm in diameter and appear as “droplets”. Another subgroup appears to have stretched, foam-like structure that can be described as material globules interconnected via smaller in diameter columns. Such particles often contain nanometer size fibers attached on their surface. In other cases, only the globules have been preserved suggesting that they may be associated with a collapsed foam structure under the dynamic pressure as it traverses in air. These distinct features originate in the structure of the superheated material during volume boiling just prior to the ejection of the particles.
Surface particulate contamination on optics can lead to laser-induced damage hence limit the performance of high power laser system. In this work we focus on understanding the fundamental mechanisms that lead to damage initiation by metal contaminants. Using time resolved microscopy and plasma spectroscopy, we studied the dynamic process of ejecting ~30 μm stainless steel particles from the exit surface of fused silica substrate irradiated with 1064 nm, 10 ns and 355 nm, 8 ns laser pulses. Time-resolved plasma emission spectroscopy was used to characterize the energy coupling and temperature rise associated with single, 10-ns pulsed laser ablation of metallic particles bound to transparent substrates. Plasma associated with Fe(I) emission lines originating from steel microspheres was observe to cool from <24,000 K to ~15,000 K over ~220 ns as τ-0.22, consistent with radiative losses and adiabatic gas expansion of a relatively free plasma. Simultaneous emission lines from Si(II) associated with the plasma etching of the SiO2 substrate were observed yielding higher plasma temperatures, ~35,000 K, relative to the Fe(I) plasma. The difference in species temperatures is consistent with plasma confinement at the microsphere-substrate interface as the particle is ejected, and is directly visualized using pump-probe shadowgraphy as a function of pulsed laser energy.
The modeling of laser interaction with metals for various applications requires a knowledge of absorption coefficients for real, commercially available materials with engineering grade (unpolished, oxidized) surfaces. However, most currently available absorptivity data pertain to pure metals with polished surfaces or vacuum-deposited thin films in controlled atmospheres. A simple laboratory setup is developed for the direct calorimetric absorptivity measurements using a diode-array laser emitting at 780 nm. A scheme eliminating the effect of convective and radiative losses is implemented. The obtained absorptivity results differ considerably from existing data for polished pure metals and are essential for the development of predictive laser-material interaction models.
Interpretation of spatial and time resolved images of rear surface ns laser damage in dielectrics requires understanding of
the dynamic interaction of the incoming laser beam with the confined expanding plasma in the material. The detailed
kinetics of the plasma, involving both expansion and retraction, depends on details of reflection and absorption in the hot
material. The growth of the hot region is treated using a model previously developed to understand laser peening. The
pressure is found to scale as the square root of laser intensity and drops off slowly after energy deposition is complete.
For the conditions of our experimental observations in fused silica, our model predicts a pressure of about 9 GPa and a
surface expansion velocity of about 1.5 km/sec, in good agreement with experimental observation.
Surface modification of fused silica windows caused by the laser ablation of surface-bound microparticles is
investigated. Using optical and electron microscopies between laser pulses, we detail the ablation, fragmentation
and dispersal of 2-150 μm diameter particles of various materials. Following complete ablation and ejection of all
debris material, surface pitting was found to be highly dependent on material type and particle size. Subsequent
light propagation modeling based on pit morphology indicates up to ~4x intensification. Understanding this class of
non-local, debris-generated damage is argued to be important for effective design of high-power optical windows
and debris-mitigation strategies.
Crater formation that accompanies laser-induced damage is the result of material ejection following the rapid, localized
heating to temperatures on the order of 1 eV. The objective of this work is to compare the material ejection behavior in
fused silica and KDP crystals as captured using time-resolved shadowgraphy. These two materials are of fundamental
importance in ICF class laser systems but they also represent materials with significantly different physical properties.
We hypothesize that these different properties can affect the material ejection process.
The modulation instability (MI) in optical fiber amplifiers and lasers with anomalous dispersion leads to CW beam
breakup and the growth of multiple pulses. This can be both a detrimental effect, limiting the performance of
amplifiers, and also an underlying physical mechanism in the operation of MI-based devices. Here we revisit the
analytical theory of MI in fiber optical amplifiers. The results of the exact theory are compared with the previously
used adiabatic approximation model, and the range of applicability of the latter is determined. The same technique is
applicable to the study of spatial MI in solid state laser amplifiers and MI in non-uniform media.
Tissue that has undergone significant yet unknown amount of ischemic injury is frequently encountered in organ
transplantation and trauma clinics. With no reliable real-time method of assessing the degree of injury incurred in tissue,
surgeons generally rely on visual observation which is subjective. In this work, we investigate the use of optical
spectroscopy methods as a potentially more reliable approach. Previous work by various groups was strongly suggestive
that tissue autofluorescence from NADH obtained under UV excitation is sensitive to metabolic response changes. To
test and expand upon this concept, we monitored autofluorescence and light scattering intensities of injured vs. uninjured
rat kidneys via multimodal imaging under 355 nm, 325 nm, and 266 nm excitation as well as scattering under 500 nm
illumination. 355 nm excitation was used to probe mainly NADH, a metabolite, while 266 nm excitation was used to
probe mainly tryptophan to correct for non-metabolic signal artifacts. The ratio of autofluorescence intensities derived
under these two excitation wavelengths was calculated and its temporal profile was fit to a relaxation model. Time
constants were extracted, and longer time constants were associated with kidney dysfunction. Analysis of both the
autofluorescence and light scattering images suggests that changes in microstructure tissue morphology, blood
absorption spectral characteristics, and pH contribute to the behavior of the observed signal which may be used to obtain
tissue functional information and offer predictive capability.
The use of reduced nicotinamide adenine dinucleotide (NADH) fluorescence to gain metabolic information on kidneys in response to an alteration in oxygen availability has previously been experimentally demonstrated, but signal quantification has not, to date, been addressed. In this work the relative contribution to rat kidney autofluorescence of the capsule versus cortex under ultraviolet excitation is determined from experimental results obtained using autofluorescence microscopy and a suitable mathematical model. The results allow for a quantitative assessment of the relative contribution of the signal originating in the metabolically active cortex as a function of capsule thickness for different wavelengths.
KEYWORDS: Laser induced damage, Silica, Current controlled current source, Laser optics, Optical damage, High power lasers, Laser systems engineering, Laser irradiation, Laser damage threshold
Laser-induced growth of optical damage often determines the useful lifetime of an optic in a high power laser system. We
have extended our previous work on growth of laser damage in fused silica with simultaneous 351 nm and 1053 nm laser
irradiation by measuring the threshold for growth with various ratios of 351 nm and 1053 nm fluence. Previously we reported
that when growth occurs, the growth rate is determined by the total fluence. We now find that the threshold for growth is
dependent on both the magnitude of the 351 nm fluence as well as the ratio of the 351 nm fluence to the 1053 nm fluence.
Furthermore, the data suggests that under certain conditions the 1053 nm fluence does not contribute to the growth.
In the clinical trials it was shown, that characteristics of optical scattering and absorption are sensitive to the tissue type
and state. In the given report improved optical biopsy system will be presented, clinical trials of which have been
conducted in the Regional Oncology Center of Nizhny Novgorod, Russia. During a year more than 160 patients with
breast tumors were investigated using this system. Radiation from a xenon lamp through an optical fiber placed inside
the probe's needle was delivered into the breast. The radiation scattered from the breast tissue was collected by another
fibers also placed in the same needle and its spectrum was measured. Obtained optical data was analyzed to find general
optical characteristics of scattered radiation in different types of tissue and revealing the major peculiarities in the spectral scattering coefficients of malignant tumors and their distinctions from benign tumors and healthy tissue. Using different mathematical algorithm the typical template of scattering spectrum was found for benign and malignant type of breast tumor. Then the algorithm of automatic detection of malignant spectra in the data flow was developed. Using this algorithm the datasets of all patients were processed and analyzed and the diagnoses were obtained. The automatic diagnoses were compared with those given by physicians. As a result the indexes of sensitivity and specificity for the optical biopsy diagnostic method were found equal to 96% and 80% correspondingly.
Currently, most of our thinking about the defects responsible for initiating laser damage considers them as featureless
absorbers. However, an increasing body of evidence, particularly involving multi-wavelength irradiation, suggests
electronic structure of damage initiators is important in determining both initiation and conditioning behaviors in KDP.
The effective absorption coefficient of energy under multi-wavelength irradiation cannot be accounted for by a
structureless absorber, but is consistent with an initiator with a multi-level structure. We outline the evidence and assess
the ability of such a simple multi-level model to explain these and other experimentally observed behaviors.
Growth of laser initiated damage plays a major role in determining optics lifetime in high power laser systems. Previous
measurements have established that the lateral diameter grows exponentially. Knowledge of the growth of the site in the
propagation direction is also important, especially so when considering techniques designed to mitigate damage growth,
where it is required to reach all the subsurface damage. In this work, we present data on both the diameter and the depth
of a growing exit surface damage sites in fused silica. Measured growth rates with both 351 nm illumination and with
combined 351 nm and 1054 nm illumination are discussed.
R. Yamamoto, J. Parker, K. Allen, R. Allmon, K. Alviso, C. Barty, B. Bhachu, C. Boley, A. Burnham, R. Combs, K. Cutter, S. Fochs, S. Gonzales, R. Hurd, K. LaFortune, W. Manning, M. McClelland, R. Merrill, L. Molina, C. Parks, P. Pax, A. Posey, M. Rotter, B. Roy, A. Rubenchik, T. Soules, D. Webb
Lawrence Livermore National Laboratory (LLNL) has been developing compact solid state lasers since the 1990's. One of the first lasers to be developed utilized flashlamp pumped architecture and neodymium glass as the laser gain media. In the early 2000's, a diode pumped version of the original flashlamp pumped laser was designed and built, responding to the requirements that a laser system for the military be compact in both size and weight while creating significant power (~100 kW) for the missions envisioned. This paper will discuss the evolution of solid state lasers at LLNL and provide a glimpse into the types of capabilities that could be achieved in the near future.
The presence of a nearby free surface means the morphology of surface damage sites is inevitably different from that of bulk damage sites. In both, the material is subject to compressive stress waves from the initial release of laser energy. However, reflection at the free surface leads to a tensile stress wave. Because material strength is much less against tension than compression, surface sites will be more extensive than bulk sites, all else being equal. We analyze the extent of damage as a function of the amount and position of energy released and compare to experimental results.
J. Adams, J. Jarboe, C. Carr, M. Feit, R. Hackel, J. Halpin, J. Honig, L. Lane, R. Luthi, J. Peterson, D. Ravizza, F. Ravizza, A. Rubenchik, W. Sell, J. Vickers, T. Weiland, T. Wennberg, D. Willard, M. Yeoman
Previous work [1] has shown the optimum pulse length range for laser-conditioning tripler-cut DKDP with 355 nm (3ω)
light lies between 200 ps and 900 ps for damage initiated at 3 ns. A 3ω, 500 ps (500 ps) table-top laser system has been
built at Lawrence Livermore National Laboratory (LLNL) [2] to take advantage of this optimal conditioning pulse length
range. This study evaluates parameters important for practically utilizing this laser as a raster-scan conditioning laser
and for determining the effectiveness of various conditioning protocols. Damage density vs. test fluence (ρ(Φ) was
measured for unconditioned and 500-ps laser-conditioned (conditioned) DKDP with 3ω, 3 ns (3 ns) test pulses. We find
a 2.5X improvement in fluence in the 3 ns ρ(Φ) after conditioning with 500 ps pulses to 5 J/cm2. We further determine
that the rate of improvement in ρ(Φ)decreases at the higher conditioning fluences (i.e. 3.5 - 5 J/cm2). Single-shot
damage threshold experiments at 500 ps were used to determine the starting fluence for our 500 ps conditioning ramps.
We find 0%, 70%, and 100% single-shot damage probability fluences of 4, 4.5, and 5 J/cm2, respectively at 500 ps. Bulk
damage size distributions created at 3 ns are presented for unconditioned and conditioned DKDP. The range of
diameters of bulk damage sites (pinpoints) in unconditioned DKDP is found to be 4.6 ± 4.4 µm in agreement with
previous results. Also, we observe no apparent difference in the bulk damage size distributions between unconditioned
and conditioned DKDP for testing at 3 ns.
Growth of laser initiated damage is a potential lifetime limiter of laser optics. While laser initiated damage occurs most often on the exit surface of optical components, some damage sites can occur on the input surface. We have investigated the growth of laser initiated damage in fused silica when the damage occurs on the input surface of the optic. We have measured both the threshold for growth as well as the lateral growth rate at 351 nm. The lateral growth of damage on the input surface is best described as having a linear dependence on shot number. The rate of growth has a linear dependence on fluence, with an extrapolated threshold of approximately 6 J/cm2. This behavior will be contrasted to growth of damage when located on the exit surface. The behavior will be compared to growth of input surface damage when the irradiation wavelength is 1053 nm or 527 nm.
We summarize recent investigations of the density and morphology of bulk damage in KDP crystals as a function of pulse duration, temporal profile, wavelength, and energy fluence. As previously reported by Runkel et al.1, we also find that the size of bulk damage sites varies roughly linearly with pulse duration for pulses between 1 ns and 9 ns. However this trend no longer applies at pulse durations below 1 ns. Experiments measuring the damage density and size distribution as a function of wavelength confirm many previous works which indicated a strong dependence of damage density with wavelength. However, we also find that the size of damage sites is relatively insensitive to wavelength. Further we see damage due to Flat-In-Time (FIT) pulses has different pulse length and fluence dependence than Gaussian pulses. We demonstrate that a simple thermal diffusion model can account for observed differences in damage densities due to square and Gaussian temporally shaped pulses of equal fluence. Moreover, we show that the key laser parameter governing size of the bulk damage sites is the length of time the pulse remains above a specific intensity. The different dependences of damage density and damage site size on laser parameters suggest different absorption mechanisms early and late in the damaging pulse.
In laser systems using frequency conversion, multiple wavelengths will be present on optical components. We have investigated the growth of laser initiated damage in fused silica in the presence of multiple wavelengths. In particular, we measured growth at 351 nm in the presence of 1053 nm near the threshold of growth for 351 nm alone. The data shows that the sum fluence determines the onset of growth as well as the growth rate. The measured growth coefficient is consistent with all the energy being delivered at 351 nm. Additionally, we measured growth at 527 nm in the presence of 1053 nm near the threshold of growth at 527 nm alone. In this case, the sum fluence also determines the growth coefficient but the rate is consistent with all the energy being delivered at 1053 nm. We present the measurements and discuss possible reasons for the behavior.
The Feit-Rubenchik size-selection damage model has been extended in a number of ways. More realistic thermal deposition profiles have been added. Non-spherical shapes (rods and plates) have been considered, with allowance for their orientation dependence. Random variations have been taken into account. An explicit form for the change of absorptivity with precursor size has been added. A simulation tool called GIDGET has been built to allow adjustment of the many possible parameters in order to fit experimental data of initiation density as a function of fluence and pulse duration. The result is a set of constraints on the possible properties of initiation precursors.
An experimental technique has been utilized to measure the variation of bulk damage scatter with damaging fluence in plates of KH2PO4 (KDP) crystals. Bulk damage in unconditioned and laser-conditioned doubler-cut KDP crystals has been studied using 527 nm (2ω) light at pulselengths of 0.3 - 10 ns. It is found that there is less scatter due to damage at fixed fluence for longer pulselengths. In particular, there is ~4X increase in fluence for equivalent scatter for damage at 2ω, 10 ns as compared to 0.30 ns in unconditioned KDP. The results for the unconditioned and conditioned KDP show that for all the pulselengths the scatter due to the bulk damage is a strong function of the damaging fluence (θ~5). It is determined that the 2ω fluence pulselength-scaling for equivalent bulk damage scatter in unconditioned KDP varies as τ0.30±0.11 and in 3ω, 3ns ramp-conditioned KDP varies as τ0.27±0.14. The effectiveness of 2ω and 3ω laser conditioning at pulselengths in the range of 0.30-23 ns for damage induced 2ω, 3 ns is analyzed in terms of scatter. For the protocols tested (i.e. peak conditioning irradiance, etc.), the 3ω, 300 ps conditioning to a peak fluence of 3 J/cm2 had the best performance under 2ω, 3 ns testing. The general trend in the performance of the conditioning protocols was shorter wavelength and shorter pulselength appear to produce better conditioning for testing at 2ω, 3 ns.
Laser conditioning, i.e. pre-exposure to less than damaging laser fluence, has been shown to improve the damage resistance of KDP/DKDP frequency conversion crystals. We have extended our damage model, small absorbing precursors with a distribution of sizes, to describe various damage related properties such as damage density and effects of laser conditioning in crystals. The model assumes the rate limiting process for both initiation and conditioning depends on temperature and that separate threshold temperatures exist for either conditioning or damage initiation to occur. This is reasonable in KDP/DKDP since the melting temperature is far below the temperatures associated with plasma formation and damage events. This model is capable of accounting for some recently observed damage-conditioning behaviors.
The effective lifetime of a laser optic is limited by both laser-induced damage and the subsequent growth of laser initiated damage sites. We have measured the growth rate of laser-induced damage on polished fused silica surfaces in 10 torr of air at 1053 nm at 10 ns. The data shows exponential growth in the lateral size of the damage site with shot number above a threshold fluence. The size of the initial damage influences the threshold for growth. We will compare the growth rates for input and output surface damage. Possible reasons for the observed growth behavior are discussed.
Spectral emission from optical breakdown in the bulk of a transparent dielectric contains information about the nature of the breakdown medium. We have made time resolved measurements of the breakdown induced emission caused by nanosecond and femtosecond infrared laser pulses. We previously demonstrated that the emission due to ns pulses is blackbody in nature allowing determination of the fireball temperature and pressure during and after the damage event. The emission due to femtosecond pulse breakdown is not blackbody in nature; two different spectral distributions being noted. In one case, the peak spectral distribution occurs at the second harmonic of the incident radiation, in the other the distribution is broader and flatter and presumably due to continuum generation. The differences between ns and fs breakdown emission can be explained by the differing breakdown region geometries for the two pulse durations. The possibility to use spectral emission as a diagnostic of the emission region morphology will be discussed.
Bulk damage sites in frequency conversion crystals scatter and/or absorb laser light leading to interference and downstream intensification .We find that laser induced bulk damage sites in DKDP exhibit a "shell" of structurally and/or chemically modified material surrounding a central core as indicated by SEM and optical micrographs and micro Raman spectral maps. We hypothesize that the modified material has been shock wave densified and estimate the amount of densification and its effect on scattering. A simple model indicates that densification of several percent is likely and that the scattering cross section may be larger than the geometric area of the inner core by an order of magnitude.
An experimental technique has been developed to measure the damage density ρ(Φ) variation with fluence from scatter maps of bulk damage sites in plates of KD2PO4 (DKDP) crystals combined with calibrated images of the damaging beam's spatial profile. Unconditioned bulk damage in tripler-cut DKDP crystals has been studied using 351 nm (3ω) light at pulse lengths of 0.055, 0.091, 0.30, 0.86, 2.6, and 10 ns. It is found that there is less scatter due to damage at fixed fluence for longer pulse lengths. The results also show that for all the pulse lengths the scatter due to damage is a strong function of the damaging fluence. It is determined that the pulse length scaling for bulk damage scatter in unconditioned DKDP material varies as τ0.24±0.05 over two orders of magnitude of pulse lengths. The effectiveness of 3ω laser conditioning at pulse lengths of 0.055, 0.096, 0.30, 0.86, 3.5, and 23 ns is analyzed in term of damage density ρ(Φ) at 3ω, 2.6 ns. The 860 ps conditioning to a peak irradiance of 7 GW/cm2 had the best performance under 3ω, 2.6 ns testing. It is shown that the optimal conditioning pulse length appears to lies in the range from 0.3 to 1 ns with a low sensitivity of 0.5 J/cm2/ns to the exact pulse length.
Laser damage of large optics initiates at material imperfections. Absorbers of very small, nanoscale size are possible initiators. We will analyze experimental implications of assuming that the damage is initiated by a size distribution of nanoabsorbers. We will demonstrate that the model predicts damage fluence pulselength scaling consistent with experiment. The size distribution of nanoabsorbers is related to the resulting damage site density and to the shape of the damage probability curve (S-curve). Conditioning of KDP crystals can be explained within the same model. The relative efficiency of various conditioning strategies is discussed.
A numerical model of CO2 laser mitigation of damage growth in fused silica has been constructed that accounts for laser energy absorption, heat conduction, radiation transport, evaporation of fused silica and thermally induced stresses. This model will be used to understand scaling issues and effects of pulse and beam shapes on material removal, temperatures reached and stresses generated. Initial calculations show good agreement of simulated and measured material removal. The model has also been applied to LG-770 glass as a prototype red blocker material.
Cracks can affect laser damage susceptibility in three ways. These are field intensification due to interference, enhanced absorption due to trapped material in the cracks, and increased mechanical weakness. Enhanced absorption is the most important effect.
Collagen possesses a strong second order nonlinear susceptibility; when it is irradiated with intense laser light, some of the reflected and transmitted light will have twice the frequency of the incident beam, a phenomenon known as second harmonic generation (SHG). Polarization modulation of an ultra-short pulse laser beam can be used to simultaneously measure collagen fiber orientation, SHG intensity, and a parameter related to the second order non-linear susceptibility. This technique has made it possible to discriminate among patterns of fibrillar orientation in many tissues. In the present study the role that organizational complexity plays in the relationship between nonlinear optical properties and collagen structure is investigated. As a component of tissues and organs, collagen’s structure and function is inextricably intertwined with that of the many other matrix components; to what extent do these noncollagenous components affect its nonlinear properties? To answer this, we investigated SHG in two different collagenous tissues, liver and cartilage; in addition we looked at the effect of progressive pathological changes in these tissues on SHG. At the other end of the spectrum, we studied collagen organized at the minimal level of complexity necessary for SHG detection: fibrils generated from solutions containing only a single type of collagen. Data obtained from these studies suggest that collagen’s strong nonlinear susceptibility, a property no other biologically significant macromolecule shares to the same degree, may serve as more than the basis of a novel imaging device for soft tissue. Collagen’s nonlinear optical properties in conjunction with its vast capacity for self-initiated conformational change--through self-assembly, site recognition, post-translational modification, and the like -make it an attractive candidate molecule for any of several demanding engineering applications, such as nanopatterning.
The effects of structural perturbation on second harmonic generation in collagen were investigated. Type I collagen fascicles obtained from rat tails were structurally modified by increasing nonenzymatic cross-linking, by thermal denaturation, by collagenase digestion, or by dehydration. Changes in polarization dependence were observed in the dehydrated samples. Surprisingly, no changes in polarization dependence were observed in highly crosslinked samples, despite significant alterations in packing structure. Complete thermal denaturation and collagenase digestion produced samples with no detectable second harmonic signal. Prior to loss of signal, no change in polarization dependence was observed in partially heated or digested collagen.
The raster scan technique is used for large optics damage tests and laser conditioning. We show that the "effective area" concept enables the possibility to compare various scanning schemes and to use raster scan experiments for NIF optics damage prediction. It is shown that the hexagonal lattice of laser beam imprints yields optimal use of each shot for most of the typically used parameters. The effects of beam fluence fluctuations and pointing inaccuracies on experiments are evaluated. To analyze raster scan conditioning experiments, we introduce the concept of "effective dose," i.e. total dose averaged over a unit cell of the scan lattice. This allows various scanning schemes to be compared quantitatively.
Theoretical models for heating, evaporation, material flow, and stress and strain generation accompanying CO2 laser damage mitigation and surface treatment of fused silica are developed to aid understanding of scaling with process parameters. We find that lateral nonlinear heat transport is an important cooling mechanism, more significant than evaporative cooling. Scaling laws relating experiments with different set of parameters are presented. Transverse conduction, together with the increased thermal conductivity at high temperatures, allows a gentle evaporation regime at low laser intensity in which the rate can be controlled via laser fluence. For higher laser intensity, recoil momentum imparted by rapid evaporation generates pressure, which can lead to transverse flow of the melted material. Only a very thin layer can flow because viscosity increases rapidly with depth. Evaporation and flow are subject to instabilities that can impact surace quality, especially surface flatness, if large areas are processed. Also material flow can heal cracks and improve material quality. Analysis of stress indicates that maximal tensile streses of order 0.1 GPa, comparable to the tensile strength, can be generated.
We use polarization-modulated second harmonic generation to image fiber orientation in collagen tissues, with an axial resolution of about 10 micrometers and a transverse resolution of up to 1 micrometers . A linearly polarized ultra-short pulse (200 fs) Ti:Sapphire laser beam is modulated using an electro-optic modulator and quarter-wave plate combination and focused onto a translation stage mounted sample using a microscope objective. The generated second harmonic light is collected using a photomultiplier tube and demodulated using phase sensitive detection to obtain signal intensity and fiber orientation information. In order to obtain second harmonic generation images of different types of collagen organization, we analyze several different tissues, including rat-tail tendon, mouse aorta, mouse fibrotic liver, and porcine skin. We can use our technique to image fibrotic tissue in histological sections of damaged liver and to identify burned tissue in porcine skin to a depth of a few hundred microns. Polarization-modulated second harmonic generation potentially could be a useful clinical technique for diagnosing collagen related disease or damage, especially in the skin.
High power laser pulses can produce damage in high quality fused silica optics that can lead to its eventual obscuration and failure. Current models suggest the initiation of a plasma detonation due to absorbing initiators and defects, leading to the formation of shock waves. Recent experiments have found a densified layer at the bottom of damage sites, as evidence of the laser-damage model. We have studied the propagation of shock waves through fused silica using molecular dynamics. These simulations show drastic modifications in the structure and topology of the network, in agreement with experimental observations.
Embedded gold and mechanical deformation in silica were used to investigate initiation of laser-induced damage at 355 nm (7.6 ns). The nanoparticle-covered surfaces were coated with between 0 and 500 nm of SiO2 by e-beam deposition. The threshold for observable damage and initiation site morphology for these engineered surfaces was determined. The gold nanoparticle coated surfaces with 500 nm SiO2 coating exhibited pinpoint damage threshold of <0.7 J/cm2 determined by light scattering and Nomarski microscopy. The gold nanoparticle coated surfaces with the 100 nm SiO2 coatings exhibited what nominally appeared to be film exfoliation damage threshold of 19 J/cm2 via light scattering and Nomarski microscopy. With atomic force microscopy pinholes could be detected at fluences greater than 7 J/cm2 and blisters at fluences greater than 3 J/cm2 on the 100-nm-coated surfaces. A series of mechanical indents and scratches were made in the fused silica substrates using a non-indentor. Plastic deformation without cracking led to damage thresholds of approximately 25 J/cm2, whereas indents and scratches with cracking led to damage thresholds of only approximately 5 J/cm2. Particularly illuminating was the deterministic damage of scratches at the deepest end of the scratch, as if the scratch acted as a waveguide.
Laser damage of large fused silica optics initiates at imperfections. Possible initiation mechanisms are considered. We demonstrate that a model based on nanoparticle explosions is consistent with the observed initiation craters. Possible mechanisms for growth upon subsequent laser irradiation, including material modification and laser intensification, are discussed. Large aperture experiments indicate an exponential increase in damage size with number of laser shots. Physical processes associated with this growth and a qualitative explanation of self-accelerated growth is presented. Rapid growth necessitates damage growth mitigation techniques. Several possible mitigation techniques are mentioned, with special emphasis on CO2 processing. Analysis of material evaporation, crack healing, and thermally induced stress are presented.
We report a summary of the surface damage, growth mitigation effort at 3(omega) for fused silica optics at LLNL. The objective was to experimentally validate selected methods that could be applied to pre-initiated or retrieved-from- service optics, to stop further damage growth. A specific goal was to obtain sufficient data and information of successful methods for fused silica optics to select a single approach for processing NIF optics. This paper includes the test results and the evaluation thereof, for several mitigation methods for fused silica. The mitigation methods tested in this study are wet chemical etching, cold plasma etching, CO2 laser processing, and micro-flame torch processing. We found that CO2 laser processing produces the most significant and consistent results to halt laser-induced surface damage growth on fused silica. We recorded successful mitigation of the growth of laser-induced surface damage sites as large as 0.5-mm diameter, for 1000 shots at fluences in the range of 8 to 13 J/cm2. We obtained sufficient data for elimination of damage growth using CO2 laser processing on sub-aperture representative optics, to proceed with application to full- scale NIF optics.
We have investigated the flash of light that accompanies laser damage using time-resolved spectroscopy. Damage events were initiated in the bulk of both fused silica and DKDP crystals with 355-nm 3-ns pulsed radiation. Spectra from the accompanying flash were recorded in the 200-500 nm wavelength range with 5-ns temporal resolution. Ten ns following damage initiation, the spectra were found to be roughly blackbody with temperatures on the order of 5000 K to 7000 K, depending on the material studied and excitation energy used. The observed temperatures and cooling rates can be related to the size and electron density of the plasma fireball that initiates the damage event.
The measurement of the second order nonlinear susceptibility of collagen in various biological tissues has potential applications in the detection of structural changes which are related to different pathological conditions. We investigate second harmonic generation in a rat-tail tendon, a highly organized collagen structure consisting of parallel fibers. Using an electro-optic modulator and a quarter-wave plate, we modulate the linear polarization of an ultra-short pulse laser beam that is used to measure second harmonic generation in a confocal microscopy setup. Phase-sensitive detection of the generated signal, coupled with a simple model of the collagen protein structures, allows us to measure a parameter (gamma) related to nonlinear susceptibility and to determine the relative orientation of the structures. Our preliminary results indicate that it may be possible to use this parameter to characterize the structure.
The effective lifetime of optics in the UV is limited both by laser induced damage and the subsequent growth of laser initiated damage sites. We have measured the growth rate of laser induced damage in fused silica in both air and vacuum. The data shows exponential growth in the lateral size of the damage site with shot number above threshold fluence. The concurrent growth in depth follows a linear dependence with shot number. The size of the initial damage influences the threshold for growth; the morphology of the initial site depends strongly on the initiating fluence. We have found only a weak dependence on pulse length for growth rate. Low fluence conditioning in air may delay the onset of growth. Most of the work has been on bare substrates but the presence of a sol-gel AR coating has no significant effect.
General physical relations connect the expected size and depth of laser damage induced craters to absorbed laser energy and to the strength of the material. In general, for small absorbers and instantaneous energy release, one expects three regions of interest. First is an inner region in which material is subjected to high pressure and temperature, pulverized and ejected. The resultant crater morphology will appear melted. A second region, outside the first, exhibits material removal due to spallation, which occurs when a shock wave is reflected at the free surface. The crater surface in this region will appear fractured. Finally, there is an outermost region where stresses are strong enough to crack material, but not to eject it. These regions are described theoretically and compared to representative observed craters in fused silica.
Results are reported from recently performed bulk-damage, pulse-scaling experiments on DKDP tripler samples taken from NIF-size, rapid-growth boule BD7. The tests were performed on LLNL's Optical Sciences Laser. A matrix of samples was exposed to single shots at 351 nm (3(omega) ) with average fluences from 4 to 8 J/cm2 for pulse durations of 1, 3 and 10 ns. The damage sites were scatter-mapped after testing to determine the damage evolution as a function of local beam fluence. The average bulk damage microcavity (pinpoint) density varied nearly linearly with fluence with peak values of approximately 16,000 pp/mm3 at 1 ns, 10,000 pp/mm3 at 3 ns and 400 pp/mm3 at 10 ns for fluences in the 8-10 J/cm2 range. The average size of a pinpoint was 10(+14,-9) micrometers at 1 ns, 37+/- 20 micrometers at 3 ns and approximately 110 micrometers at 10 ns, although all pulse durations produced pinpoints with a wide distribution of sizes. Analysis of the pinpoint density data yielded pulse-scaling behavior of t0.35. Significant planar cracking around the pinpoint as was observed for the 10 ns case but not for the 1 and 3 ns pulses. Crack formation around pinpoints has also been observed frequently for Zeus ADT tests at approximately 8 ns. The high pinpoint densities also lead to significant eruption of near-surface bulk damage. Measurements of the damage site area for surface and bulk gave ratios (Asurf/Abulk) of 2:1 at 1 ns, 7:1 at 3 ns and 110:1 at 10 ns.
Recent LLNL experiments reported elsewhere at this conference explored the pulse length dependence of 351 nm bulk damage incidence in DKDP. The results found are consistent, in part, with a model in which a distribution of small bulk initiators is assumed to exist in the crystal, and the damage threshold is determined by reaching a critical temperature. The observed pulse length dependence can be explained as being set by the most probable defect capable of causing damage at a given pulse length. Analysis of obscuration in side illuminated images of the damaged region yields estimates of the damage site distributions that are in reasonable agreement with the distributions experimentally directly estimated.
Femtosecond laser ablation has been shown to produce well-defined cuts and holes in metals with minimal heat effect to the remaining material. Ultrashort laser pulse processing shows promise as an important technique for materials processing. We will discuss the physical effects associated with processing based experimental and modeling results. Intense ultra-short laser pulse (USLP) generates high pressures and temperatures in a subsurface layer during the pulse, which can strongly modify the absorption. We carried out simulations of USLP absorption versus material and pulse parameters. The ablation rate as function of the laser parameters has been estimated. Since every laser pulse removes only a small amount of material, a practical laser processing system must have high repetition rate. We will demonstrate that planar ablation is unstable and the initially smooth crater bottom develops a corrugated pattern after many tens of shots. The corrugation growth rate, angle of incidence and the polarization of laser electric field dependence will be discussed. In the nonlinear stage, the formation of coherent structures with scales much larger than the laser wavelength was observed. Also, there appears to be a threshold fluence above which a narrow, nearly perfectly circular channel forms after a few hundred shots. Subsequent shots deepen this channel without significantly increasing its diameter. The role of light absorption in the hole walls will be discussed.
A confocal microscopy imaging system was devised to selectively detect second harmonic signals generated by biological tissues. Several types of biological tissues were examined using this imaging system, including human teeth, bovine blood vessels, and chicken skin. All these tissues generated strong second harmonic signals. There is considerable evidence that the source of these signals in tissue is collagen. Collagen, the predominant component of most tissues, is known to have second order nonlinear susceptibility. This technique may have diagnostic usefulness in pathophysiological conditions characterized by changes in collagen structure including malignant transformation of nevi, progression of diabetic complications, and abnormalities in wound healing.
A Mach-Zehnder interferometer was used for analysis of pressure waves generated by ultrashort laser pulse ablation of water. It was found that the shock wave generated by plasma formation rapidly decays to an acoustic wave. Both experimental and theoretical studies demonstrated that the energy transfer to the mechanical shock was less than 1%.
The use of femtosecond lasers allows materials processing of practically any material with extremely high precision and minimal collateral damage. Advantages over conventional laser machining (using pulses longer than a few tens of picoseconds) are realized by depositing the laser energy into the electrons of the material on a time scale short compared to the transfer time of this energy to the bulk of the material, resulting in increased ablation efficiency and negligible shock or thermal stress. The improvement in the morphology by using femtosecond pulses rather than nanosecond pulses has been studied in numerous materials from biological materials to dielectrics to metals. During the drilling process, we have observed the onset of small channels which drill faster than the surrounding material.
A confocal microscopy imaging system was devised to selectively detect second harmonic signals generated by biological tissues. Several types of biological tissues were examined using this imaging system, including human teeth, bovine blood vessels, and chicken skin. All these tissues generated strong second harmonic signals. There is considerable evidence that the source of these signals in tissue is collagen. Collagen, the predominant component of most tissues, is known to have second order nonlinear susceptibility. This technique may have diagnostic usefulness in pathophysiological conditions characterized by changes in collagen structure including malignant transformation of nevi, progression of diabetic complications, and abnormalities in wound healing.
Expansion of ablation plumes created by intense ultrashort lasers is determined by various complicated physical processes which have very different spatial and time scales. Since complete simulation by one model is practically impossible, we suggest using two models describing initial and final stages that can be matched at an intermediate time. The proposed modeling procedure connects laser parameters to plume properties far away from the ablation spot. Laser material interaction and beginning of the expansion are simulated with a one-dimensional hydrodynamics code and the final stage is modeled using an analytical solution for an expanding three- dimensional ellipsoidal gas cloud.
We describe simulations of experiments invovling laser illumination of a metallic knife edge in the Optical Sciences Laboratory (OSL) at LLNL, and pinhole closure in the Beamlet experiment at LLNL. The plasma evolution is modeled via LASNEX. In OSL, the calculated phases of a probe beam are found to exhibit the same behavior as in experiment but to be consistently larger. The motion of a given phase contour tends to decelerate at high intensities. At fixed intensity, the speed decreases with atomic mass. We then calculate the plasma associated with 4-leaf pinholes on the Beamlet transport spatial filter. We employ a new propagation code to follow a realistic input beam through the entire spatial filter, including the plasmas. The detailed behavior of the output wavefronts is obtained. We show how closure depends on the orientation and material of the pinholes blades. As observed in experiment, a diamond orientation is preferable to a square orientation, and tantalum performs better than stainless steel.
Fused silica windows were artificially contaminated to estimate the resistance of target chamber debris shields against laser damage during NIF operation. Uniform contamination thin films were prepared by sputtering various materials. The loss of transmission of the samples was first measured. They were then tested at 355 nm in air with an 8- ns Nd:YAG laser. The damage morphologies were characterized by Nomarski optical microscopy and SEM. Both theory and experiments showed that metal contamination for films as thin as 1 nm leads to a substantial los of transmission. The laser damage resistance dropped very uniformly across the entire surface. The damage morphology characterization showed that contrary to clean silica, metal coated samples did not produce pits on the surface, B4C coated silica, on the other hand, led to a higher density of such damage pits. A model for light absorption in the thin film was coupled with a simple heat deposition and diffusion model to perform preliminary theoretical estimates of damage thresholds. The estimates of the loss due to light absorption and reflection pointed out significant differences between metals. The damage threshold predictions were in qualitative agreement with experimental measurements.
Understanding the 'extreme statistics' of failure at a weak link allows extrapolation of the results of small area laser damage tests to predict damage levels for the large areas pertinent to NIF/LMJ. Conceptually, it is important to focus on the fluence dependence of the surface density of damage sites. Results of different types of damage tests can be reported in terms of this sample characteristic property.
A novel photothermal microscopy (PTM) is developed which uses only one laser beam, working as both the pump and the probe. The principle of this single-beam PTM is based on the detection of the second harmonic component of the laser modulated scattering (LMS) signal. This component has a linear dependence on the optical absorptance of the tested area and a quadratic dependence on the pump laser power. Using a pump laser at the wavelengths of 514.5- and 532-nm high-resolution photothermal scans are performed for polished fused silica surfaces and a HfO2/SiO2 multilayer coatings. The results are compared with those from the traditional two-beam PTM mapping. It is demonstrated that the single-beam PTM is more user-friendly than conventional two-beam PTM and, offers a higher spatial resolution for defect detection.
Laser modulated scattering (LMS) is introduced as a non- destruction evaluation tool for defect inspection and characterization of optical surface sand thin film coatings. It allows simultaneous measurement of the DC and AC scattering signals of a probe laser beam from an optical surface. by comparison between the DC and AC scattering signals, one can differentiate absorptive defects from non- absorptive ones. This paper describes the principle of the LMS technique and the experimental setup, and illustrates examples on using LMS as a tool for nondestructive evaluation of high quality optics.
For the aggressive fluence requirements of the NIF laser, some level of laser-induced damage to the large 351 nm final optics is inevitable. Planning and utilization of NIF therefore requires reliable prediction of the functional degradation of the final optics. Laser damage test are typically carried out with Gaussian beams on relatively small test ares. The test yield a damage probability vs. energy fluence relation. These damage probabilities are shown to depend on both the beam fluence distribution and the size of area tested. Thus, some analysis is necessary in order to use these test results to determine expected damage levels for large aperture optics. We present a statistical approach which interprets the damage probability in terms of an underlying intrinsic surface density of damaging defects. This allows extrapolation of test results to different sized areas and different beam shapes. The defect density is found to vary as a power of the fluence.
Plasma luminescence spectroscopy was used for precise ablation of bone tissue without damaging nearby soft tissue using an ultrashort pulse laser. Strong contrast of the luminescence spectra between bone marrow and spinal cord provided the real time feedback control so bone tissue is selectively ablated while preserving the spinal cord.
Temperature and shock wave propagation in water (as a model of tissue) irradiated by sub-picosecond and nanosecond pulses were modeled. The high temperature and pressure generated during sub-picosecond irradiation did not penetrate deeply into the water due to quickly ejected plasma while significant pressure and temperature increases were observed in deep regions with nanosecond pulses. Knowing that the sub- picosecond pulses are effective for tissue ablation, additional studies were done to examine the effect of short pulse widths (less than 20 ps). Ablation threshold, temperature rise and ablation crater quality on human dentine were investigated for different pulse widths in the range of 150 fs - 20 ps. The ablation threshold fluence was approximately 4 times higher with 20 ps pulses than with 150 fs pulses but the quality of the alation craters were not significantly different in this pulse width range.
A set of fused silica windows were artificially contaminated by sputtering various thin film materials onto the surface to simulate target chamber contamination of high fluence optical components. The samples were then tested 1/1 and N/1 at 355 nm in air and vacuum with a 3- ns Nd:YAG laser to measure the damage threshold as a function of film thickness and film composition. The damage morphologies were characterized by Nomarski optical microscopy and SEM. The results show that thin film contamination leads to a decrease in damage threshold. The test also show a difference in damage behavior between air and vacuum. The results were compared to a model of the absorption of laser light in the film, shockwave generation and reflection, and heating dependence on film composition and thickness.
Starting from the absorption of laser energy at a subsurface nanoparticle in fused silica, we simulate the consequent buildup of stresses and resulting mechanical material damage. The simulation indicates the formation of micropits with size comparable to a wavelength, similar to experimental observation. Possible mechanism for enhanced local light absorption are discussed.
Assuming the observed scaling of laser damage threshold fluence with the (almost) square root of pulse duration is due to thermal conduction, we develop a formalism for directly comparing pulses of different shapes and durations. We find, for example, that a top hat pulse leads to 15% higher temperature (presumably 15% lower damage threshold) than a Gaussian pulse of the same fluence. We also find that the damage threshold of the expected NIF type pulse should be estimated from a Gaussian pulse with the same peak intensity. We find that the deviation of the scaling of damage threshold from square root of pulse duration has contributions from both the small but finite size of laser energy absorbers and from the temperature dependence of thermal properties. Keywords: laser damage, damage threshold, scaling, thermal conduction
The laser architecture of the NIF beamlines requires small- area beam dumps to safely absorb back reflections from the output and leakage through the PEPC switch. The problems presented by these beam dumps are that fluences they must absorb are very large, beyond the damage threshold of any material, and ablation of beam dump materials potentially contaminates adjacent optical components. Full scale tests have demonstrated that a stainless steel beam dump will survive fluence levels and energies as high as 820 J/cm2 and 2.5 kJ, respectively. Small scale tests with tungsten, tantalum, and stainless steel have demonstrated erosion rates less than about 0.5 micrometers /shot, with stainless steel having the smallest rate. They also suggest that increased angles of incidence (>= 60 degree(s)) will greatly reduce the material ablated directly back along the beam path.
We are engaged in a comprehensive effort to understand and model the initiation and growth of laser damage initiated by surface contaminants. This includes, for example, the initial absorption by the contaminant, heating and plasma generation, pressure and thermal loading of the transparent substrate, and subsequent shockwave propagation, `splashing' of molten material and possible spallation, optical propagation and scattering, and treatment of material fracture. The integration use of large radiation hydrodynamics codes, optical propagation codes and material strength codes enables a comprehensive view of the damage process.
Nonabsorbing bulk defects can initiate laser damage in transparent materials. Defects such as voids, microcracks and localized stress concentrations can serve as positive or negative lenses for the incident laser light. The resulting interference pattern between refracted and diffracted light can result in intensity increases on the order of a factor of 2 some distance away from a typical negative microlens, and even larger for a positive microlens. Thus, the initial damage site can be physically removed from the defect which initiates damage. The parameter that determines the strength of such lensing is (Ka)2 (Delta) (epsilon) where the wavenumber K is 2(pi) /(lambda) , 2a is the linear size of the defect and (Delta) (epsilon) is the difference in dielectric coefficient between matrix and scatterer. Thus, even a small change in refractive index results in a significant effect for a defect large compared to a wavelength. Geometry is also important. 3D (eg. voids) as well as linear and planar (eg. cracks) microlenses can all have strong effects. The present paper evaluates the intensification due to spherical voids and high refractive index inclusions. We wish to particularly draw attention to the very large intensification that can occur at inclusions.
Experiments and calculations indicate that the threshold pressure in spatial filters for distortion of a transmitted pulse scales approximately as I-0.2 and (F#)2 over the intensity range from 1014 to 2 X 1015 W/cm2. We also demonstrated an interferometric diagnostic that will be used to measure the scaling relationships governing pinhole closure in spatial filters.
The validity of an extended Rayleigh model for laser generated bubbles in soft tissue is examined. This model includes surface tension, viscosity, a realistic water equation of state, material strength and failure, stress wave emission and linear growth of interface instabilities. It is compared to detailed dynamic simulations using the computer program LATIS. These simulations include stress wave propagation, a realistic water equation of state, material strength and failure, and viscosity. The extended Rayleigh model and the detailed dynamic simulations are compared using a 1D spherical geometry with a bubble in the center and using a 2D cylindrical geometry of a laser fiber immersed in water with a bubble formed at the end of the fiber. Studies are done to test the validity of the material strength and failure, stress wave emission, and the interface instability terms in the extended Rayleigh model. The resulting bubble radii, material damage radii, the emitted stress wave energies, and the size of the interface distortions are compared. Conclusions are made on the validity of the extended Rayleigh model and on possible improvements to this model. The purpose of this study is to investigate the use of the extended Rayleigh model as a substitute for the detailed dynamic simulations when only limited information is needed. It is also meant to benchmark the detailed dynamic simulations when only limited information is needed. It is also meant to benchmark the detailed dynamic simulations and highlight the relevant physics. It is shown that the extended Rayleigh model executes over 300 times faster on a computer than the detailed dynamic simulations.
Nonabsorbing defects can lead to laser damage. Defects such as voids, microcracks and localized stressed concentrations, even if they differ from the surrounding medium only be refractive index, can serve as positive or negative lenses of the incident laser light. The resulting interference pattern between refracted and diffracted light can result in intensity increases on the order of a factor of 2 some distance away from a typical negative microlens, and even larger for a positive microlens. Thus, the initial damage site can be physically removed from the defect which initiates damage. The parameter that determines the strength of such lensing is (Ka)2 (Delta) (epsilon) where the wave number K is 2(pi) /(lambda) , 2a is the linear size of the defect and (Delta) (epsilon) is the difference in dielectric coefficient between matrix and scatterer. Thus, even a small change in refractive index results in a significant effect for a defect large compared to a wavelength. Geometry is also important. 3D as well as linear and planar microlens can all have strong effects. The present paper evaluates the intensification due to spherical voids and high refractive index inclusions.
We are engaged in a comprehensive effort to understand and model the initiation and growth of laser damage initiated by surface contaminants. This includes, for example, the initial absorption by the contaminant, heating and plasma generation, pressure and thermal loading of the transparent substrate, and subsequent shockwave propagation, 'splashing' of molten material and possible spallation, optical propagation and scattering, and treatment of material fracture. The integration use of large radiation hydrodynamics codes, optical propagation codes and material strength codes enables a comprehensive view of the damage process. On the entrance optical surface, small particles can ablate nearly completely. In this case, only relatively weak shockwaves are launched into the substrate, but some particulate materials may be left on the surface to act as a diffraction mask and cause further absorption. DIffraction by wavelength scale scattering centers can lead to significant intensity modulation. Larger particles will not be completely vaporized. The shockwave generated in this case is larger and can lead to spallation of contaminant material which then may be deposited in the substrate. A gaseous atmosphere can lead to radiation trapping with concomitant increases in temperature and pressure near the surface. In addition, supersonic ionization waves in air may be generated which greatly extend the plasma plume spatially and temporally. Contaminants on the exit optical surface behave differently. They tend to heat and pop off completely in which case significant damage may not occur. Since plasma formed at the interface of the optic and absorbing particle is confined, much stronger pressures are generated in this case. Imaging of contaminants resulting in 'writing' a diffraction pattern on the exit surface due to contamination on the entrance surface has been observed experimentally and predicted theoretically. Such imprinted damage regions can seed damage from subsequent pulses.
Advances in high peak power short-pulse laser systems are currently limited by laser-induced damage to optical components by the intense short pulses. We have investigated the damage thresholds and mechanisms of pure dielectrics, and gold and multilayer-dielectric mirrors and diffraction gratings, with pulses ranging from 1 ns down to 0.1 ps. Theoretical modeling of the damage process is in quantitative agreement with measurements for both metals and dielectrics. In the dielectrics, we find a change in pulse width scaling of the threshold fluence near 20 ps, below which the excited electrons generated by multiphoton and avalanche ionization have insufficient time to couple their energy to the lattice during the pulse. For the shortest pulses the damage process becomes dominated by multiphoton ionization, leading to a very strong dependence on the electric field strength (extremely localized ablation) and a relative insensitivity to sample defects.
Lasers are currently limited in their ability to remove hard tissue. Furthermore, many laser systems, such as the long pulse infrared lasers used to ablate bone or hard dental tissue, also generate unacceptable heat levels and cause collateral tissue damage. Ultrashort pulse lasers, however, are highly efficient, quiet and relatively free of damage. With recent development now allowing operation at high pulse repetition rates, ultrashort pulse systems can yield significant material volume removal which can potentially match or even exceed conventional technology while still maintaining the minimal collateral damage characteristics. In this paper, we report on preliminary studies of 350 fs pulse interactions with hard tissue and compare our results to the nanosecond ablation regime.
A computational model for the ablation of tooth enamel by ultra-short laser pulses is presented. The role of simulations using this model in designing and understanding laser drilling systems is discussed. Pulses of duration 300 fsec and intensity greater than 1012 W/cm2 are considered. Laser absorption proceeds via multi-photon initiated plasma mechanism. The hydrodynamic response is calculated with a finite difference method, using an equation of state constructed from thermodynamic functions including electronic, ion motion, and chemical binding terms. Results for the ablation efficiency are presented. An analytic model describing the ablation threshold and ablation depth is presented. Thermal coupling to the remaining tissue and long-time thermal conduction are calculated. Simulation results are compared to experimental measurements of the ablation efficiency. Desired improvements in the model are presented.
Tissue ablation with ultrashort laser pulses offers several unique advantages. The nonlinear energy deposition is insensitive to tissue type allowing this tool to be used for soft and hard tissue ablation. The localized energy deposition leads to precise ablation depth and minimal collateral damage. In this paper we will report on our efforts to study and demonstrate tissue ablation using an ultrashort pulse laser. The ablation efficiency, and extent of collateral damage for 0.3 ps and 1000 ps duration laser pulses will be compared. Temperature measurements of the rear surface of a tooth section will also be presented.
In spite of intensive research, lasers have not replaced conventional tools in many hard tissue applications. Low removal rates, loud operation noise, and mechanical and thermal damage are among the main obstacles to successful application of lasers. Ultrashort pulse lasers offer several advantages in their high per-pulse-efficiency, negligible thermal and mechanical damage and low noise operation. Practical applications of these devices, however, depends critically on sufficiently high volume removal which should match or even exceed the high speed drill. In our study, acoustical output of the USPL is compared to the low and high speed dental drill, Er:YAG, and Ho:YSGG lasers. Noise levels of the USPL are shown to be negligible in comparison with all other tested system. In addition, thermal characteristics of hard dental tissue ablation by ultrashort pulse laser of low and high pulse repetition rates are presented. Encouraging results showing temperatures increases smaller than 10 degree(s)C even at the highest pulse repetition rates (1 KHz) are presented. A simple model for heat diffusion is discussed.
In spite of intensive research, lasers have not replaced conventional tools in many hard tissue applications. Ultrashort pulse lasers offer several advantages in their highly per-pulse-efficient operation, negligible thermal and mechanical damage and low noise operation. Possible development of optimal laser systems to replace the high-speed dental drill is discussed. Applications of ultrashort pulse systems for dental procedures are outlined. Selection criteria and critical parameters are considered, and are compared to the conventional air-turbine drill and to long and short pulsed systems.
An overview of the physics of dental tissue processing with ultra-short pulse lasers is presented. Due to the small ablation rate per pulse, multiple pulses are necessary for macroscopic material removal. The paper discusses the cumulative effect of multiple pulse processing. Experimental data and calculation of thermal loading are presented, and the optimal laser system repetition rate is estimated. Modeling of the crater produced by multiple pulses is presented and possibilities to control the crater shape are discussed.
Ultrashort laser pulse tissue ablation has demonstrated advantages of greatly reduced required energy and collateral damage. These advantages stem directly from the fact that laser energy is absorbed nonlinearly in a time too short for significant thermal and hydrodynamic response. The high peak power and short pulse duration both have implications for practical fiber delivery systems.
Lasers are currently limited in their ability to remove hard tissue. Furthermore, many laser systems, such as the long pulse infrared lasers used to ablate bone or hard dental tissue, also generate unacceptable heat levels and cause collateral tissue damage. Ultrashort pulse lasers, however, are highly efficient, quiet, and relatively free of charge. With recent developments now allowing operation at high pulse repetition rates, ultrashort pulse systems can yield significant material volume removal which can potentially match or even exceed conventional technology while still maintaining the minimal collateral damage characteristics. In this paper, the interaction characteristics of two pulse regimes with enamel and dentin: 350 fs pulse ablation of hard dental tissues is compared to the interaction with one nanosecond pulses. Ablation rates were characterized and surface morphology, and structure were evaluated using a scanning electron microscope.
A computational model for the ablation of tooth enamel by ultra-short laser pulses is presented. The role of simulations using this model in designing and understanding laser drilling systems is discussed. Pulses of duration 300 fsec and intensity greater than 1012 W/cm2 are considered. Laser absorption proceeds via multi-photon initiated plasma mechanism. The hydrodynamic response is calculated with a finite difference method, using an equation of state constructed from thermodynamic functions including electronic, ion motion, and chemical binding terms. Results for the ablation efficiency are presented. An analytic model describing the ablation threshold and ablation depth is presented. Thermal coupling to the remaining tissue and long-time thermal conduction are calculated. Simulation results are compared to experimental measurements of the ablation efficiency. Desired improvements in the model are presented.
Chirped pulse amplification is increasingly used to produce intense ultrashort laser pulses. When high efficiency gratings are the dispersive element, as in the LLNL Petawatt laser, their susceptibility to laser induced damage constitutes a limitation on the peak intensities that can be reached. To obtain robust gratings, it is necessary to understand the causes of short-pulse damage, and to recognize the range of design options for high efficiency gratings. Metal gratings owe their high efficiency to their high conductivity. To avoid the inevitable light absorption that accompanies conductivity, we have developed designs for high efficiency reflection gratings that use only transparent dielectric materials. These combine the reflectivity of a multilayer dielectric stack with a diffraction grating. We report here our present understanding of short-pulse laser induced damage, as it applies to dielectric gratings.
Nonlinear self-focusing in laser glass imposes limits on the energy fluence that can be safely transmitted without risking damage. For this reason, it is desirable to strictly limit the peak to average spatial variations of fluence by smoothing schemes such as smoothing by spectral dispersion (SSD). While spatial variations are problematic, the same is not necessarily true of temporal variations since normal group velocity dispersion tends to smooth out temporal peaks caused by spatial self-focusing. Earlier work indicated that increased bandwidth can delay the onset of self focusing. Indeed, a point can be reached at which self phase modulation nonlinearly increases the bandwidth, changing the speckle statistics along with suppressing self focusing. Unfortunately, this study found that a large initial bandwidth (compared with the gain bandwidth) was necessary to achieve this suppression under practical conditions. The full calculation for modulated beams was carried out for one transverse dimension. Two transverse dimensional calculations only treated symmetric beams. The present work reexamines the question of self focusing threshold increases due to high bandwidth by investigating another source of such increase in three dimensional beam breakup -- the bending instability. For simplicity, we consider the behavior of a single space-time speckle. Normal dispersion can lead to splitting of the pulse and delay of self focusing for short enough pulses as noted above. In addition to the self focusing instability, the laser beam is also subject to the so-called bending (sausage like) instability which can spatially disperse the field maxima over time. Because the bending instability breaks an initial axial symmetry, a full three dimensional numerical simulation is required to study it accurately. Such calculations are possible, but costly. We have used a modified 2D nonlinear Schrodinger equation with a high power nonlinearity since this mimics the 3D behavior of the competition between self focusing and bending. This allows a semi-quantitative estimate to be made of the possible significance of the bending instability for suppression of self focusing.
Our extensive measurements of damage thresholds for fused silica and several fluorides (LiF, CaF, MgF, and BaF) at 1053 and 526 nm for pulse durations, (tau) , ranging from 275 fs to 1 ns are reported elsewhere at this meeting. A theoretical model based on electron production via multiphoton ionization, Joule heating, and collisional (avalanche) ionization is in good agreement with experimental results.
Plasma mediated ablation of collagen gels and porcine cornea was studied at various laser pulse durations in the range from 350 fs to 1 ns at 1053 nm wavelength. A time resolved stress detection technique was employed to measure transient stress profiles and amplitudes. Optical microscopy was used to characterize ablation craters qualitatively, while a wide band acoustic transducer helped to quantify tissue mechanical response and the ablation threshold. The ablation threshold was measured as a function of laser pulse duration and linear absorption coefficient. For nanosecond pulses the ablation threshold was found to have a strong dependence on the linear absorption coefficient of the material. As the pulse length decreased into the subpicosecond regime the ablation threshold became insensitive to the linear absorption coefficient. High quality ablation craters with no thermal or mechanical damage to surrounding material were obtained with 350 fs laser pulses. The mechanism of optical breakdown at the tissue surface was theoretically investigated. In the nanosecond regime, optical breakdown proceeds as an electron collisional avalanche ionization initiated by thermal seed electrons. These seed electrons are created by heating of the tissue by linear absorption. In the ultrashort pulse range, optical breakdown is initiated by the multiphoton ionization of the irradiated medium (6 photons in case of tissue irradiated at 1053 nm wavelength), and becomes less sensitive to the linear absorption coefficient. The energy deposition profile is insensitive to both the laser pulse duration and the linear absorption coefficient.
We report laser-induced damage threshold measurements on pure and multilayer dielectrics and gold-coated optics at 1053 and 526 nm for pulse durations, (tau) , ranging from 140 fs to 1 ns. Damage thresholds of gold coatings are limited to 500 mJ/cm2 in the subpicosecond range from 1053-nm pulses. In dielectrics, qualitative differences in the morphology of damage and a departure from the diffusion-dominated (tau) 1/2 scaling indicate that damage results from plasma formation and ablation for (tau) <EQ 10 ps and from conventional melting and boiling for (tau) > 50 ps. A theoretical model based on electron production via multiphoton ionization, Joule heating, and collisional (avalanche) ionization is in quantitative agreement with both the pulsewidth and wavelength scaling of experimental results.
A new method of film structure monitoring is proposed. It is based on the analysis of second harmonic (SH) radiation induced in a film irradiated by a laser beam. SH intensity measurement versus angle of the plane of polarization of the incident light and versus film thickness provides the information about film crystal quality, presence of polycrystalline component and crystallographic axes orientation. This method can be complementary to the well-known ones and is especially suitable for research groups since it allows a correlation between technological and crystallographic parameters to be quickly determined.
A new method of film structure in situ monitoring is proposed for MBE (molecular beam epitaxy) and MOCVD technologies. It is based on the analysis of second harmonic (SH) radiation induced in a growing film irradiated by a laser beam. SH intensity measurement versus angle of polarization plane of the incident light and versus film thickness provides the in situ information about film crystal quality, presence of polycrystal component, and crystallographic axes orientation. This method can be complementary to the well-known technique of fast electron diffraction (RHEED) and is supposed to be especially suitable for research groups since it allows a correlation between technological and crystallographic parameters to be quickly determined.
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