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5 October 2023 Spectroscopic probing of non-thermal reactant activation in plasmon-catalyzed reactions
Zee Hwan Kim, Hyun-Hang Shin, Jaeyoung Jeong, Hyungjun Park
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Proceedings Volume PC12654, Enhanced Spectroscopies and Nanoimaging 2023; PC1265405 (2023) https://doi.org/10.1117/12.2676095
Event: SPIE Nanoscience + Engineering, 2023, San Diego, California, United States
Abstract
Recent studies on plasmon-assisted chemical reactions postulate that the hot carriers of plasmon-excited nanostructures may induce a non-thermal vibrational activation of metal-bound reactants. However, a quantitative validation at the level of molecular quantum states is currently missing. I will present our recent spectroscopic studies on metal-bound reactants, which directly proves the non-thermal vibrational molecular excitations caused by plasmons.
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Zee Hwan Kim, Hyun-Hang Shin, Jaeyoung Jeong, and Hyungjun Park "Spectroscopic probing of non-thermal reactant activation in plasmon-catalyzed reactions", Proc. SPIE PC12654, Enhanced Spectroscopies and Nanoimaging 2023, PC1265405 (5 October 2023); https://doi.org/10.1117/12.2676095
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KEYWORDS
Spectroscopy
Vibration
Chemical reactions
Molecular spectroscopy
Hot carriers
Metals
Nanostructures
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