Paper
6 March 2014 Optomechanical manipulation of chemical reactions on the nanoscale with optofluidic nanotweezers
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Abstract
Chemical reactions are often described as a progression along a reaction coordinate. Waveguide evanescent fields generate an electromagnetic force that spans tens of nanometers and have been used previously to trap protein molecules. Applying this force along a reaction coordinate could radically alter the chemical reaction by modifying the activation energy or biasing the reaction towards a specific pathway. Here, we show that the adsorption of proteins onto carbon nanotubes can be controlled with opto-mechanical forces. An analytic model for the reaction was developed, the predictions of which were explored by probing the energy barrier under various experimental conditions.
© (2014) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Dakota O'Dell, Xavier Serey, and David Erickson "Optomechanical manipulation of chemical reactions on the nanoscale with optofluidic nanotweezers", Proc. SPIE 8976, Microfluidics, BioMEMS, and Medical Microsystems XII, 897613 (6 March 2014); https://doi.org/10.1117/12.2040138
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Cited by 1 scholarly publication.
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KEYWORDS
Adsorption

Proteins

Waveguides

Carbon nanotubes

Molecules

Chemical reactions

Luminescence

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