Paper
12 February 2010 Depolarized scattering of silver nanostructures in dye-less sensing
Pabak Sarkar, Tanya Shtoyko, Rafal Luchowski, Nils Calander, Aby Roth, Anne-Marie Brun-Zinkernagel, Zygmunt Gryczynski, Ignacy Gryczynski
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Abstract
Scattering from noble metallic nanoparticles with specific structures are strongly depolarized in contrast to dielectric particles. The effect depends on the shape and symmetry of the nanoparticles and can be explained by induced plasmonic multi-resonances along different axes of symmetry. In our experiments we found that the scattering from 'nanorod' structures of silver is more polarized than globular colloidal silver nanostructures. The depolarized scattering can be tuned to the near-infrared region by using proportionate mixture of the colloids and nanorods. We demonstrate this effect in solution as well as in polymer films where nanoparticles were immobilized. This phenomenon of depolarized scattering is promising for designing dye-less sensing devices useful in diagnostics. We show scattering polarization profile from asymmetric nanostructures changes during their aggregation. Modulating the rate of aggregation of these nanostructures by 'receptor - ligand'-like interactions can be successfully utilized for sensitive 'dye-less' diagnostics.
© (2010) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Pabak Sarkar, Tanya Shtoyko, Rafal Luchowski, Nils Calander, Aby Roth, Anne-Marie Brun-Zinkernagel, Zygmunt Gryczynski, and Ignacy Gryczynski "Depolarized scattering of silver nanostructures in dye-less sensing", Proc. SPIE 7574, Nanoscale Imaging, Sensing, and Actuation for Biomedical Applications VII, 75740V (12 February 2010); https://doi.org/10.1117/12.841392
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KEYWORDS
Scattering

Nanorods

Light scattering

Particles

Silver

Dielectrics

Nanoparticles

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