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We demonstrate a simple approach to significantly reduce the electrical resistivity of thermo-responsive shape-memory
polymers (SMPs), so that they can be easily triggered for shape recovery by Joule heating at a low electrical voltage.
After adding a small amount of Ni micro particles into a polyurethane SMP filled with carbon black (CB), the electrical
resistivity is slightly reduced. However, if these Ni particles are aligned into chains (by applying a low magnetic field on
SMP/CB/Ni solution and then drying to fix the conductive chains), the drop of electrical resistivity is significant. This
kind of SMP composites is suitable for cyclic operation as only micro/nano particles are used. A sample (40×15×1mm)
with 10vol% of CB and 0.5vol% of chained Ni can be heated to 80°C for shape recovery at 30 V (1.2 W) of power. This
approach is generic and applicable for producing other conductive polymers.
Xin Lan,Wei Min Huang,Na Liu,Sy Phee,Jin Song Leng, andShan Yi Du
"Improving the electrical conductivity by forming Ni powder chains in a shape-memory polymer filled with carbon black", Proc. SPIE 6927, Electroactive Polymer Actuators and Devices (EAPAD) 2008, 692717 (15 April 2008); https://doi.org/10.1117/12.776546
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Xin Lan, Wei Min Huang, Na Liu, Sy Phee, Jin Song Leng, Shan Yi Du, "Improving the electrical conductivity by forming Ni powder chains in a shape-memory polymer filled with carbon black," Proc. SPIE 6927, Electroactive Polymer Actuators and Devices (EAPAD) 2008, 692717 (15 April 2008); https://doi.org/10.1117/12.776546