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New aspects of RCOB structure were obtained from Eu3+ absorption/emission spectra in GdCOB and EuCOB host lattices. The spectra of Eu3+ in powders and single crystals are comparatively analyzed. The Eu3+ spectra show at least three non-equivalent centers whose static spectral characteristics were used to assign structural modes. An explanation of the difference between GdCOB: Eu3+ and EuCOB spectra in terms of a disordered occupancy of rare earth and calcium sites is given.
E. Antic-Fidancev,Aurelia Lupei, andGerard Aka
"Optical analysis of the local perturbation in RCOB host lattice doped with europium ion", Proc. SPIE 5581, ROMOPTO 2003: Seventh Conference on Optics, (21 October 2004); https://doi.org/10.1117/12.582799
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E. Antic-Fidancev, Aurelia Lupei, Gerard Aka, "Optical analysis of the local perturbation in RCOB host lattice doped with europium ion," Proc. SPIE 5581, ROMOPTO 2003: Seventh Conference on Optics, (21 October 2004); https://doi.org/10.1117/12.582799