Structure property relationship study on new cubane-1,4-dicarboxylic acid derivatives

Gyula Benyei; Istvan Jalsovszki; Katalin Fodor-Csorba

doi:10.1117/12.581058

1 September 2004 Structure property relationship study on new cubane-1,4-dicarboxylic acid derivatives

Gyula Benyei, Istvan Jalsovszki, Katalin Fodor-Csorba

Proceedings Volume 5565, XV Conference on Liquid Crystals; (2004) https://doi.org/10.1117/12.581058
Event: XV Conference on Liquid Crystals, 2003, Zakopane, Poland

Abstract

Three new series of cubane-1,4-dicarboxylic acid derivatives have been prepared as bis[(4'-alkyl)phenyl]cubane-1,4-dicarboxylates, bis[(4'-alkoxy)phenyl]cubane-1,4-dicarboxylates, and two chiral derivatives as bis(cholestenyl)cubane-1,4-dicarboxylate and (S)- bis{4'-[(2-methylbutyl)oxycarbonyl}phenyl}cubane-1,4-dicarboxylate. These ester type compounds have the bulky cubane skeleton as a central building block in their core system. The lower homologues of the alkoxyphenyl ester series exhibited nematic, the higher ones smectic A phase. The mesophase formation was supressed in case of the (4-alkyl)phenyl- and chiral derivatives.

Citation Download Citation

Gyula Benyei, Istvan Jalsovszki, and Katalin Fodor-Csorba "Structure property relationship study on new cubane-1,4-dicarboxylic acid derivatives", Proc. SPIE 5565, XV Conference on Liquid Crystals, (1 September 2004); https://doi.org/10.1117/12.581058

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