Raman spectra of S=O vibrations of dimethylsulphoxide in liquid state

A. Jumabaev; F. H. Tukhvatullin; U. N. Tashkenbaev; Z. Mamatov

doi:10.1117/12.451389

1 November 2002 Raman spectra of S=O vibrations of dimethylsulphoxide in liquid state

A. Jumabaev, F. H. Tukhvatullin, U. N. Tashkenbaev, Z. Mamatov

Proceedings Volume 4812, Nonlinear Spectroscopy; (2002) https://doi.org/10.1117/12.451389
Event: International Symposium on Optical Science and Technology, 2002, Seattle, WA, United States

Abstract

Quasiempirical calculations of stable molecular aggregations for dimethylsulfoxide were carried out by MINDO/3 method. The structure of the aggregates and energy of its formation for cases of two, three and four molecules were determined. It was shown that except monomer molecules are possible aggregations from two or three molecules. It was established that the aggregations form by charge interaction of polar molecules. Apparently in liquid state of substance the tendency of aggregation formation remains. The presence of three imposed bands in Raman spectra of S=O vibrations for dimethylsulfoxide was connected, on our opinion, with this. The difference of depolarization ratio for imposed bands is connected with different distribution of charge on S=O bond for different aggregations.

Citation Download Citation

A. Jumabaev, F. H. Tukhvatullin, U. N. Tashkenbaev, and Z. Mamatov "Raman spectra of S=O vibrations of dimethylsulphoxide in liquid state", Proc. SPIE 4812, Nonlinear Spectroscopy, (1 November 2002); https://doi.org/10.1117/12.451389

ACCESS THE FULL ARTICLE

INSTITUTIONAL
Select your institution to access the SPIE Digital Library.

SELECT YOUR INSTITUTION

PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.

PERSONAL SIGN IN

No SPIE Account? Create one

PURCHASE THIS CONTENT

SUBSCRIBE TO DIGITAL LIBRARY

50 downloads per 1-year subscription

Members: $195

Non-members: $335 ADD TO CART

25 downloads per 1 - year subscription

Members: $145

Non-members: $250 ADD TO CART

PURCHASE SINGLE ARTICLE

Includes PDF, HTML & Video, when available