Paper
18 May 1999 4-ms response time in a photorefractive polymer
Jon A. Herlocker, Kyle B. Ferrio, Eric Hendrickx, Brett D. Guenther, Stephane Mery, Bernard Kippelen, Nasser Peyghambarian
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Abstract
Efficient photorefractive polymers hold great potential for optical data processing and storage and so have been a topic of intense investigations in recent years. Materials with nearly 100 percent diffraction efficiencies have been developed, but these have been generally characterized by much slower response than their less efficient inorganic counterparts. In this report, we describe a 4-ms initial rise-time using a visible-transparent chromophore in a PVK- based polymer of Tg equals 39 degrees C for 48-V/micrometers bias projected along the grating vector and 250-mW/cm2 writing beams. This fast component consistently accounts for 90 percent of the steady-state response and is analyzed as a function of bias field. We also present transient ellipsometry measurements of an orientational response significantly faster than the grating development, suggesting that chromophores alignment sped does not limit transient grating formation. We describe the role of such underlying property measurements in understanding photorefractive transient behavior, and prospects for further improvements.
© (1999) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Jon A. Herlocker, Kyle B. Ferrio, Eric Hendrickx, Brett D. Guenther, Stephane Mery, Bernard Kippelen, and Nasser Peyghambarian "4-ms response time in a photorefractive polymer", Proc. SPIE 3623, Organic Photonic Materials and Devices, (18 May 1999); https://doi.org/10.1117/12.348395
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KEYWORDS
Chromophores

Composites

Photorefractive polymers

Diffraction

Four wave mixing

Absorption

Ellipsometry

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