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For some 3 years, Ophir Optronics has been producing diamond like
carbon (DLC) coatings on germanium substrates. These coatings are
very adherent and durable and have transmission and durability
properties.
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A. Azran, U. Elfersi, Ephraim Greenfield, "Hard carbon coating on ZnS," Proc. SPIE 1442, 7th Mtg in Israel on Optical Engineering, (1 April 1991); https://doi.org/10.1117/12.49044