Er3+ and Yb3+ co-doped bismuth silicate (Bi4Si3O12, BSO) crystals were grown by a modified vertical Bridgman method for 1.5-1.6μm laser application. Fixed the ratio of Er3+ and Yb3+ at 1:9, (ErxYbyBi1-x-y)4Si3O12 crystals with 2mol%(x=0.002, y=0.018), 3mol%(x=0.003, y=0.027) and 4mol%(x=0.004, y=0.036) were obtained. Their transmittance was about 80%. The absorption spectrum shows that Er:Yb: BSO crystals have the strongest absorption peak at 976nm, which is attributed to the absorption of Yb ions, and the strongest emission peak recorded by the emission spectrum is at 1544nm, which is due to the up-conversion effect of Yb ions to Er ions, thus enhancing the emission of Er ions at 1544 nm. Among them, 3mol% co-doped BSO crystal with optimized composition of x=0.003 and y=0.027 shows the strongest absorption and emission peak. Its absorption and emission cross sections are 2.99×10-20 cm2 and 1.1452×10-20 cm2 , respectively. The results demonstrate that the Er:Yb:BSO crystals are potential material for 1.5-1.6μm laser.
|