Paper
2 November 2023 Luminescent studies of flexible [DUT-8 (Zn)] metal-organic frameworks
N. V. Slyusarenko, A. S. Krylov, M. V. Timofeeva, S. A. Shipilovskikh, E. A. Slyusareva
Author Affiliations +
Proceedings Volume 12920, XVI International Conference on Pulsed Lasers and Laser Applications; 1292014 (2023) https://doi.org/10.1117/12.3005774
Event: XVI International Conference on Pulsed Lasers and Laser Applications, 2023, Tomsk, Russian Federation
Abstract
An approach to the study of the porous structure of metal-organic frameworks (MOF) using guest luminescent molecules with specially selected spectral characteristics as acceptors of electronic excitation energy was suggested. If such molecules are adsorbed in MOF pores with sizes comparable to the Förster radius, Förster resonance energy transfer (FRET) from photoexcited linkers occurs. In this case quenching of luminescence of the linker can serve as analytical signals indicating open pore structure of the MOF. The developed approach was demonstrated by the example of DUT-8(Zn) MOF and Coumarin 1 as guest molecules by time-resolved luminescence methods.
(2023) Published by SPIE. Downloading of the abstract is permitted for personal use only.
N. V. Slyusarenko, A. S. Krylov, M. V. Timofeeva, S. A. Shipilovskikh, and E. A. Slyusareva "Luminescent studies of flexible [DUT-8 (Zn)] metal-organic frameworks", Proc. SPIE 12920, XVI International Conference on Pulsed Lasers and Laser Applications, 1292014 (2 November 2023); https://doi.org/10.1117/12.3005774
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KEYWORDS
Luminescence

Molecules

Dyes

Fluorescence resonance energy transfer

Scanning electron microscopy

Energy transfer

Raman spectroscopy

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