Presentation
11 January 2023 Accurate and fast master equation modeling of triplet-triplet annihilation in organic phosphorescent emission layers including correlations
Author Affiliations +
Abstract
Triplet-triplet annihilation (TTA) gives rise to correlations in the positions of surviving excitons, which are ignored in the mean-field approximation of the master equation (ME). These correlations can in principle be accounted for exactly in Kinetic Monte Carlo (KMC) simulations, but these are computationally expensive. In this work, we present ME modeling of TTA that accounts for correlations. A comparison between our modeling and KMC simulations reveals the effect of correlations on the rates of radiative decay and TTA, and shows that our ME modeling is an accurate and computationally attractive alternative.
Conference Presentation
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Mahyar Taherpour, Clint van Hoesel, Reinder Coehoorn, and Peter Bobbert "Accurate and fast master equation modeling of triplet-triplet annihilation in organic phosphorescent emission layers including correlations", Proc. SPIE 12336, Frontiers in Luminescent Organic Semiconductor Materials and Devices, 123360C (11 January 2023); https://doi.org/10.1117/12.2644929
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KEYWORDS
Monte Carlo methods

Excitons

Computer simulations

Organic light emitting diodes

Diffusion

Luminescence

Superposition

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