Paper
27 March 2022 Experimental investigation on environmental durability of protected-silver mirrors
Xu Xu, Wang Hang, Xiong Tao
Author Affiliations +
Proceedings Volume 12169, Eighth Symposium on Novel Photoelectronic Detection Technology and Applications; 121691P (2022) https://doi.org/10.1117/12.2622365
Event: Eighth Symposium on Novel Photoelectronic Detection Technology and Applications, 2021, Kunming, China
Abstract
Silver-based high-reflective mirrors are widely used in optical applications such as large-aperture astronomical telescopes and spaced-based optics. The long-term stability of silver-based mirrors is of great importance to these applications. The development of more durable silver-based mirrors has been a hot topic in the optical coating community. In this paper, corrosion mechanisms of the protected-silver mirrors with a Sub/NiCrNx/Ag/NiCrNx/SiNx/Air structure were investigated in details. The corrosion features of a single layer Ag sample, which exposed to atmospheric environment for a few days, are observed by a Zeta-500 3D optical microscope. The durability of protected-silver mirrors with a structure of Sub/NiCrNx/Ag/NiCrNx/SiNx/Air is evaluated by accelerated environmental tests, including 360-hour salt fog test and humidity test. A transmittance measurement setup at the wavelength of 632.8 nm and a Perkin-Elmer Lambda 1050 spectrophotometer are used to monitor the transmittance and reflectance evolutions during the accelerated environmental tests. A Zeta-500 3D optical microscope is employed to analyze the corrosion features of the protected-silver mirrors after 360-hour accelerated environmental tests. X-ray diffractometer (XRD) is employed to analyze the microstructure before and after 360-hour accelerated environmental tests. Based on the experimental results, the potential corrosion mechanisms of the protected-silver mirrors were discussed in-depth. Furthermore, it was demonstrated that the transmittance evolution, which represents the pinhole density and therefore the degree of corrosion of the protected-silver mirrors, is valuable to evaluate the durability of silver-based mirrors.
© (2022) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Xu Xu, Wang Hang, and Xiong Tao "Experimental investigation on environmental durability of protected-silver mirrors", Proc. SPIE 12169, Eighth Symposium on Novel Photoelectronic Detection Technology and Applications, 121691P (27 March 2022); https://doi.org/10.1117/12.2622365
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KEYWORDS
Mirrors

Corrosion

Silver

Fiber optic gyroscopes

Humidity

Transmittance

Reflectivity

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