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Three precursors of graphite were employed to synthesise graphite oxides (GrO) that are now routinely obtained by the oxidation of a precursor graphite. These oxidation samples exhibit highly broadened D and G Raman bands which caused by the large amount of defects of graphene sheets. In addition, chemical oxidation results in the multiple peaks such as G*, D+D` and 2D`(in place of the conventional 2D band), which are activated by defects. The broad G band might also be deconvoluted in the actual G band and D` band, thereby attributing the broadening in G band. The band position and intensity ratio have also been demonstrated in the oxidized graphite.
R. Muzyka,S. Drewniak,T. Pustelny,G. Gryglewicz, andŁ. Smędowski
"RAMAN spectroscopic study of graphite oxide obtained from different graphite precursors", Proc. SPIE 10034, 11th Conference on Integrated Optics: Sensors, Sensing Structures, and Methods, 100340C (2 September 2016); https://doi.org/10.1117/12.2244461
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R. Muzyka, S. Drewniak, T. Pustelny, G. Gryglewicz, Ł. Smędowski, "RAMAN spectroscopic study of graphite oxide obtained from different graphite precursors," Proc. SPIE 10034, 11th Conference on Integrated Optics: Sensors, Sensing Structures, and Methods, 100340C (2 September 2016); https://doi.org/10.1117/12.2244461