Dependence Of Calibration Curves Obtained From Gram-Schmidt Chromatograms From Experimental Parameters In CGC/FTIRS

Hans Malissa Jr.; Kurt Martin; Karl Winsauer

doi:10.1117/12.970844

20 December 1985 Dependence Of Calibration Curves Obtained From Gram-Schmidt Chromatograms From Experimental Parameters In CGC/FTIRS

Hans Malissa Jr., Kurt Martin, Karl Winsauer

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Proceedings Volume 0553, Fourier and Computerized Infrared Spectroscopy; (1985) https://doi.org/10.1117/12.970844
Event: 1985 International Conference on Fourier and Computerized Infrared Spectroscopy, 1985, Ottawa, Canada

Abstract

The calibration curve for quantitative evaluation of Gram-Schmidt chromatograms (GSC) show a non-linearity in the low concentration region. Systematic experiments revealed, that variation in the baseline height in the GSC is responsible for a shift in the calibration curve. Summarized results are: (1) small changes of baseline introduce relative large errors; (2) this non-linearity must also be considered, when small peaks are measured which are not completely separated from a major one.

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Hans Malissa Jr., Kurt Martin, and Karl Winsauer "Dependence Of Calibration Curves Obtained From Gram-Schmidt Chromatograms From Experimental Parameters In CGC/FTIRS", Proc. SPIE 0553, Fourier and Computerized Infrared Spectroscopy, (20 December 1985); https://doi.org/10.1117/12.970844

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